Antoine Pierre Buchard

Search results

• 2024

  Aminophosphonium organocatalysts for the ring-opening copolymerisation of epoxide and cyclic anhydride

  Clark, E. F., Dunstan, E., Kociok-Köhn, G. & Buchard, A., 22 Oct 2024, (E-pub ahead of print) In: Chemical Communications. 60, 89, p. 13067-13070 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

• Deterioration of bio-based polylactic acid plastic teabags under environmental conditions and their associated effects on earthworms

  Courtene-Jones, W., Burgevin, F., Munns, L., Shillam, M. B. T., De Falco, F., Buchard, A., Handy, R. D., Thompson, R. C. & Hanley, M. E., 15 Jul 2024, In: Science of the Total Environment. 934, 172806.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Unexpected Periodicity in Cationic Group 5 Initiators for the Ring-Opening Polymerization of Lactones

  Buchard, A., Davidson, M., Gobius Du Sart, G., Kociok-Kohn, G., McCormick, S. & McKeown, P., 8 Jan 2024, In: Inorganic Chemistry. 63, 1, p. 27-38 12 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Xylose- and Nucleoside-Based Polymers via Thiolene Polymerization toward Sugar-derived Solid Polymer Electrolytes

  Oshinowo, M., Piccini, M., Kociok-Kohn, G., Marken, F. & Buchard, A., 9 Feb 2024, In: ACS Applied Polymer Materials. 6, 3, p. 1622-1632 11 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Xylose-derived thionocarbamates as a synthetic handle towards a functional platform of sugar-based polymers

  Runge, J. R., Davies, B. & Buchard, A., 15 Jul 2024, In: Polymer Chemistry. 15, 31, p. 3149-3156 8 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access
• 2023

  A Highly Active and Selective Zirconium-Based Catalyst System for the Industrial Production of Poly(lactic acid)

  Buchard, A., Chuck, C. J., Davidson, M. G., Gobius du Sart, G., Jones, M. D., McCormick, S. N. & Russell, A. D., 17 Feb 2023, In: ACS Catalysis. 13, 4, p. 2681-2695 15 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• A molecular dynamics approach to modelling oxygen diffusion in PLA and PLA clay nanocomposites

  Lightfoot, J., Castro Dominguez, B., Buchard, A. & Parker, S. C., 24 Apr 2023, In: Materials Advances. 4, 10, p. 2281-2291 11 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Chemical Recycling of Commercial Poly(l-lactic acid) to l-Lactide Using a High-Performance Sn(II)/Alcohol Catalyst System

  McGuire, T. M., Buchard, A. & Williams, C. K., 13 Sept 2023, In: Journal of the American Chemical Society. 145, 36, p. 19840-19848 9 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Coordination of ϵ-Caprolactone to a Cationic Niobium(V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination-Insertion

  Buchard, A., Davidson, M. G., Gobius du Sart, G., Jones, M. D., Kociok-Köhn, G., McCormick, S. N. & Mckeown, P., 25 Sept 2023, In: Inorganic Chemistry. 62, 38, p. 15688–15699

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Correlating Metal Redox Potentials to Co(III)K(I) Catalyst Performances in Carbon Dioxide and Propene Oxide Ring Opening Copolymerization

  Lindeboom, W., Deacy, A. C., Phanopoulos, A., Buchard, A. & Williams, C. K., 11 Sept 2023, In: Angewandte Chemie International Edition. 62, 37, e202308378.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Crosslinking of sugar-derived polyethers and boronic acids for renewable, self-healing and single-ion conducting organogel polymer electrolytes

  Daniels, E. L., Runge, J. R., Oshinowo, M., Leese, H. & Buchard, A., 13 Mar 2023, In: ACS Applied Energy Materials. 6, 5, p. 2924-2935 12 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Evaluating Heterodinuclear Mg(II)M(II) (M = Mn, Fe, Ni, Cu, and Zn) Catalysts for the Chemical Recycling of Poly(cyclohexene carbonate): ACS Catalysis

  Smith, M. L., McGuire, T. M., Buchard, A. & Williams, C. K., 15 Dec 2023, In: ACS Catalysis. 13, 24, p. 15770-15778 9 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Polymers from sugars and isothiocyanates: ring-opening copolymerization of a D-xylose anhydrosugar oxetane

  Clark, E. F., Kociok-Köhn, G., Davidson, M. G. & Buchard, A., 22 May 2023, In: Polymer Chemistry. 14, 23, p. 2838-2847 10 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Radical Ring Opening Polymerization of Cyclic Ketene Acetals Derived From d-Glucal

  Hardy, C., Levere, M. E., Kociok-Köhn, G. & Buchard, A., 21 Nov 2023, In: ACS Macro Letters. 12, 11, p. 1443-1449 7 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Variations around the presence and position of sulfur in sugar-derived cyclic monomers: influence on polymerisation thermodynamics, polymer sequence and thermal properties

  Hardy, C., Kociok-Köhn, G. & Buchard, A., 31 Jan 2023, In: Polymer Chemistry. 14, 5, p. 623-632

  Research output: Contribution to journal › Article › peer-review

  Open Access
• 2022

  A comparative study of oxygen diffusion in PET and PEF using molecular modelling: Computational Insights into the Mechanism for Gas Transport in Bulk Polymer Systems

  Lightfoot, J., Buchard, A., Castro Dominguez, B. & Parker, S., 25 Jan 2022, In: MACROMOLECULES. 55, 2, p. 498-510 13 p.

  Research output: Contribution to journal › Article › peer-review

• Chemical Recycling of Poly(Cyclohexene Carbonate) Using a Di-MgII Catalyst

  Singer, F. N., Deacy, A. C., McGuire, T. M., Williams, C. K. & Buchard, A., 27 Jun 2022, In: Angewandte Chemie International Edition. 61, 26, e202201785.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Crosslinked xylose-based polyester as a bio-derived and degradable solid polymer electrolyte for Li+-ion conduction

  Oshinowo, M., Runge, J., Piccini, M., Marken, F. & Buchard, A., 28 Mar 2022, In: Journal of Materials Chemistry A. 10, 12, p. 6796-6808 13 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Heterometallic cooperativity in divalent metal ProPhenol catalysts: combining zinc with magnesium or calcium for cyclic ester ring-opening polymerisation

  Gruszka, W., Sha, H., Buchard, A. & Garden, J. A., 21 Feb 2022, In: Catalysis Science and Technology. 12, 4, p. 1070-1079 10 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Insights into the Mechanism of Carbon Dioxide and Propylene Oxide Ring-Opening Copolymerization Using a Co(III)/K(I) Heterodinuclear Catalyst: Journal of the American Chemical Society

  Deacy, A. C., Phanopoulos, A., Lindeboom, W., Buchard, A. & Williams, C. K., 5 Oct 2022, In: Journal of the American Chemical Society. 144, 39, p. 17929–17938

  Research output: Contribution to journal › Article › peer-review

• Solid-State Chemical Recycling of Polycarbonates to Epoxides and Carbon Dioxide Using a Heterodinuclear Mg(II)Co(II) Catalyst: Journal of the American Chemical Society

  McGuire, T. M., Deacy, A. C., Buchard, A. & Williams, C. K., 12 Oct 2022, In: Journal of the American Chemical Society. 144, 40, p. 18444–18449

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Understanding the Effects of Cross-Linking Density on the Self-Healing Performance of Epoxidized Natural Rubber and Natural Rubber

  Boden, J., Bowen, C. R., Buchard, A., Davidson, M. G. & Norris, C., 3 May 2022, In: ACS Omega. 7, 17, p. 15098-15105 8 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• UV degradation of poly(lactic acid) materials through copolymerisation with a sugar-derived cyclic xanthate

  Hardy, C. A., Kociok-Köhn, G. & Buchard, A., 4 May 2022, In: Chemical Communications. 58, 36, p. 5463-5466 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access
• 2021

  Catalytic Synergy Using Al(III) and Group 1 Metals to Accelerate Epoxide and Anhydride Ring-Opening Copolymerizations

  Diment, W. T., Gregory, G. L., Kerr, R. W. F., Phanopoulos, A., Buchard, A. & Williams, C. K., 15 Oct 2021, In: ACS Catalysis. 11, 20, p. 12532-12542 11 p.

  Research output: Contribution to journal › Article › peer-review

• Control of Crystallinity and Stereocomplexation of Synthetic Carbohydrate Polymers from D- and L-Xylose

  McGuire, T., Bowles, J., Deane, E., Farrar, E., Grayson, M. & Buchard, A., 23 Feb 2021, In: Angewandte chemie-International edition. 60, 0, p. 4524 –4528

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Does the Configuration at the Metal Matter in Noyori–Ikariya Type Asymmetric Transfer Hydrogenation Catalysts?: ACS Catalysis

  Hall, A. M. R., Berry, D. B. G., Crossley, J. N., Codina, A., Clegg, I., Lowe, J. P., Buchard, A. & Hintermair, U., 26 Oct 2021, In: ACS Catalysis. 11, 21, p. 13649-13659 11 p.

  Research output: Contribution to journal › Article › peer-review

• Polymers from sugars and CS2: ring opening copolymerisation of a D-xylose anhydrosugar oxetane

  McGuire, T. & Buchard, A., 7 Aug 2021, In: Polymer Chemistry. 12, 29, p. 4253-4261 9 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Polymers from Sugars and Cyclic Anhydrides: Ring-Opening Copolymerization of a D-Xylose Anhydrosugar Oxetane

  Mcguire, T. M., Clark, E. F. & Buchard, A., 8 Jun 2021, In: MACROMOLECULES. 54, 11, p. 5094-5105 12 p.

  Research output: Contribution to journal › Article › peer-review

• Xylose-Based Polyethers and Polyesters Via ADMET Polymerization toward Polyethylene-Like Materials: ACS Applied Polymer Materials

  Piccini, M., Lightfoot, J., Dominguez, B. C. & Buchard, A., 12 Nov 2021, In: ACS Applied Polymer Materials. 3, 11, p. 5870–5881

  Research output: Contribution to journal › Article › peer-review
• 2020

  Combining alkali metals and zinc to harness heterometallic cooperativity in cyclic ester ring-opening polymerisation

  Gruszka, W., Lykkeberg, A., Nichol, G. S., Shaver, M. P., Buchard, A. & Garden, J. A., 21 Nov 2020, In: Chemical Science. 11, 43, p. 11785-11790 6 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Epoxy-functionalised 4-vinylguaiacol for the synthesis of bio-based, degradable star polymers via a RAFT/ROCOP strategy

  McGuire, T. M., Miyajima, M., Uchiyama, M., Buchard, A. & Kamigaito, M., 28 Sept 2020, In: Polymer Chemistry. 11, 36, p. 5844-5850 7 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Indium phosphasalen catalysts showing high isoselectivity and activity in racemic lactide and lactone ring opening polymerizations

  Yuntawattana, N., McGuire, T. M., Durr, C. B., Buchard, A. & Williams, C. K., 7 Nov 2020, In: Catalysis Science and Technology. 10, 21, p. 7226-7239 14 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

• Polymers from sugars and unsaturated fatty acids: ADMET polymerisation of monomers derived from D-xylose, D-mannose and castor oil

  Piccini, M., Leak, D. J., Chuck, C. J. & Buchard, A., 21 Apr 2020, In: Polymer Chemistry. 11, 15, p. 2681-2691 11 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access
• 2019

  Copolymerization of Cyclic Phosphonate and Lactide: Synthetic Strategies toward Control of Amphiphilic Microstructure

  Beament, J., Wolf, T., Markwart, J. C., Wurm, F. R., Jones, M. D. & Buchard, A., 12 Feb 2019, In: MACROMOLECULES. 52, 3, p. 1220–1226

  Research output: Contribution to journal › Article › peer-review

• Divergent Catalytic Strategies for the Cis/Trans Stereoselective Ring-Opening Polymerization of a Dual Cyclic Carbonate/Olefin Monomer

  McGuire, T. M., Pérale, C., Castaing, R., Kociok-Köhn, G. & Buchard, A., 28 Aug 2019, In: Journal of the American Chemical Society. 141, 34, p. 13301-13305 5 p.

  Research output: Contribution to journal › Article › peer-review

• New renewably-sourced polyesters from limonene-derived monomers

  Thomsett, M., Moore, J. C., Buchard, A., Stockman, R. & Howdle, S. M., 7 Jan 2019, In: Green Chemistry. 21, 1, p. 149-156 8 p.

  Research output: Contribution to journal › Article › peer-review

• Polymer-supported metal catalysts for the heterogeneous polymerisation of lactones

  Howard, I. C., Hammond, C. & Buchard, A., 21 Nov 2019, In: Polymer Chemistry. 10, 43, p. 5894-5904 11 p.

  Research output: Contribution to journal › Article › peer-review
• 2018

  Aluminum complexes of mono-pyrrolidine ligands for the con-trolled ring opening polymerization of lactide

  Beament, J., Mahon, M., Buchard, A. & Jones, M., 11 Jun 2018, In: Organometallics. 37, 11, p. 1719-1724 6 p.

  Research output: Contribution to journal › Article › peer-review

• Bipyrrolidine salan alkoxide complexes of lanthanides: synthesis, characterisation, activity in the polymerisation of lactide and mechanistic investigation by DOSY NMR

  Beament, J., Kociok-Kohn, G., Jones, M. & Buchard, A., 2018, In: Dalton Transactions. 47, p. 9164-9172 9 p.

  Research output: Contribution to journal › Article › peer-review

• Chemoselective Lactonization of Renewable Succinic Acid with Heterogeneous Nanoparticle Catalysts

  Yakabi, K., Jones, A., Buchard, A., Roldan, A. & Hammond, C., 29 Oct 2018, In: ACS Sustainable Chemistry and Engineering. 6, 12, p. 16341–16351

  Research output: Contribution to journal › Article › peer-review

• Electrochemically Driven C-H Hydrogen Abstraction Processes with the Tetrachloro-Phthalimido-N-Oxyl (Cl4PINO) Catalyst

  Marken, F., Buckingham, M. A., Bull, S., Cunningham, W., Buchard, A., Folli, A. & Murphy, D., 1 Aug 2018, In: Electroanalysis. 30, 8, p. 1706-1713 8 p.

  Research output: Contribution to journal › Article › peer-review

• Mechanism of CO 2 capture in nanostructured sodium amide encapsulated in porous silica

  Tian, M., Buchard, A., Wells, S. A., Fang, Y., Torrente-murciano, L., Nearchou, A., Dong, Z., White, T. J., Sartbaeva, A. & Ting, V. P., 25 Sept 2018, In: Surface & coatings technology. 350, p. 227-233 7 p.

  Research output: Contribution to journal › Article › peer-review

• Polymers from sugars and CS2: synthesis and ring-opening polymerisation of sulfur-containing monomers derived from 2-deoxy- d-ribose and d-xylose

  López-vidal, E. M., Gregory, G. L., Kociok-Kohn, G. & Buchard, A., 7 Apr 2018, In: Polymer Chemistry. 9, 13, p. 1577-1582 6 p.

  Research output: Contribution to journal › Article › peer-review

• Synthesis of 5- to 8-membered cyclic carbonates from diols and CO2: A one-step, atmospheric pressure and ambient temperature procedure

  McGuire, T. M., López-Vidal, E. M., Gregory, G. L. & Buchard, A., 1 Oct 2018, In: Journal of CO2 Utilization. 27, p. 283-288 6 p.

  Research output: Contribution to journal › Article › peer-review
• 2017

  CO2-Driven stereochemical inversion of sugars to create thymidine-based polycarbonates by ring-opening polymerisation

  Gregory, G. L., Hierons, E. M., Kociok-Kohn, G., Sharma, R. I. & Buchard, A., 14 Mar 2017, In: Polymer Chemistry. 8, 10, p. 1714-1721 8 p.

  Research output: Contribution to journal › Article › peer-review

• Continuous production of bio-renewable, polymer-grade lactone monomers through Sn-β catalysed Baeyer-Villiger oxidation with H2O2

  Yakabi, K., Mathieux, T., Milne, K., Lopez-Vidal, E. M., Buchard, A. & Hammond, C., 22 Sept 2017, In: ChemSusChem. 10, 18, p. 3652–3659

  Research output: Contribution to journal › Article › peer-review

• Di-Zinc Aryl Complexes: CO2 Insertions and Applications in Polymerization Catalysis

  Romain, C., Garden, J. A., Trott, G., Buchard, A., White, A. J. P. & Williams, C. K., 29 May 2017, In: Chemistry - A European Journal. 23, 30, p. 7367–7376

  Research output: Contribution to journal › Article › peer-review

• Polymers from sugar: cyclic monomer synthesis, ring-opening polymerisation, material properties and applications

  Gregory, G. L., López-Vidal, E. M. & Buchard, A., 27 Jan 2017, In: Chemical communications. 53, 14, p. 2198-2217 20 p.

  Research output: Contribution to journal › Article › peer-review

• Polymers from sugars and CO2: Ring-opening polymerisation and copolymerisation of cyclic carbonates derived from 2-deoxy-d-ribose

  Gregory, G. L., Kociok-Kohn, G. & Buchard, A., 15 Mar 2017, In: Polymer Chemistry. 8, 13, p. 2093-2104 12 p.

  Research output: Contribution to journal › Article › peer-review

• Salan Group 13 complexes – structural study and lactide polymerisation

  Beament, J., Mahon, M., Buchard, A. & Jones, M., 7 Mar 2017, In: NEW JOURNAL OF CHEMISTRY. 41, 5, p. 2198-2203 6 p.

  Research output: Contribution to journal › Article › peer-review