Caroline Elizabeth Helen Dessent

Search results

• 2007

  Characterizing the intrinsic stability of gas-phase clusters of transition metal complex dianions with alkali metal counterions: Counterion perturbation of multiply charged anions

  Burke, R. M., Boxford, W. E. & Dessent, C. E. H., 12 Feb 2007, In: Journal of Chemical Physics. 126, 6, p. - 9 p.

  Research output: Contribution to journal › Article › peer-review

• Multidimensional Franck-Condon simulations of photodetachment spectra for the formate-water cluster anion: Investigating H atom transfer along the HCOOH+OH reaction coordinate

  Guo, J., Pugliesi, I., Mueller-Dethlefs, K. & Dessent, C. E. H., 21 Dec 2007, In: Journal of Chemical Physics. 127, 23, p. - 11 p.

  Research output: Contribution to journal › Article › peer-review

• New insights into dianion-cation contact ion-pairs: understanding the effect of cation complexation on the electron detachment and ionic fragmentation pathways of multiply charged anions

  Boxford, W. E., Burke, R. M. & Dessent, C. E. H., Sept 2007, In: Physica Scripta. 76, 3, p. C56-C62 7 p.

  Research output: Contribution to journal › Article › peer-review

• On the propensity for electron transfer in high-energy collisions of iridium complex anions with cesium atoms

  Burke, R. M., Boxford, W. E., Panja, S., Nielsen, S. B. & Dessent, C. E. H., 17 Jul 2007, In: Chemical Physics Letters. 442, 4-6, p. 201-205 5 p.

  Research output: Contribution to journal › Article › peer-review
• 2006

  Counter-ion perturbation of the fragmentation pathways of multiply charged anions: Evidence for exit channel complexes on the fragmentation potential energy surfaces

  Burke, R. M., Boxford, W. E. & Dessent, C. E. H., 14 Jul 2006, In: Journal of Chemical Physics. 125, 2, p. - 4 p.

  Research output: Contribution to journal › Article › peer-review

• Microsolvation of the chlorine oxide anion and chlorine oxide radical: Structures and energetics of the ClO-center dot(H2O)(n) and ClO center dot(H2O)n n=1-4 clusters

  Guo, J., Watkins, M. J., Mueller-Dethlefs, K. & Dessent, C. E. H., 29 Sept 2006, In: Chemical Physics Letters. 429, 1-3, p. 32-37 6 p.

  Research output: Contribution to journal › Article › peer-review

• Probing the intrinsic features and environmental stabilization of multiply charged anions

  Boxford, W. E. & Dessent, C. E. H., 2006, In: Physical Chemistry Chemical Physics. 8, 44, p. 5151-5165 15 p.

  Research output: Contribution to journal › Article › peer-review
• 2005

  High-energy collision induced dissociation of iridium hexa-halide dianions: Observation of triple electron detachment and other decay pathways

  Boxford, W. E., El Ghazaly, M. O. A., Dessent, C. E. H. & Nielsen, S. B., 15 Jun 2005, In: INTERNATIONAL JOURNAL OF MASS SPECTROMETRY. 244, 1, p. 60-64 5 p.

  Research output: Contribution to journal › Article › peer-review

• On the stability of IrCl63- and other triply charged anions: Solvent stabilization versus ionic fragmentation and electron detachment for the IrCl63-center dot(H2O)(n) n=0-10 microsolvated clusters

  Boxford, W. E. & Dessent, C. E. H., 7 Jul 2005, In: Journal of Physical Chemistry A. 109, 26, p. 5836-5845 10 p.

  Research output: Contribution to journal › Article › peer-review

• Stabilization of excess charge in isolated adenosine 5 '-triphosphate and adenosine 5 '-diphosphate multiply and singly charged anions

  Burke, R. M., Pearce, J. K., Boxford, W. E., Bruckmann, A. & Dessent, C. E. H., 3 Nov 2005, In: Journal of Physical Chemistry A. 109, 43, p. 9775-9785 11 p.

  Research output: Contribution to journal › Article › peer-review
• 2004

  Ionic fragmentation versus electron detachment in isolated transition metal complex dianions

  Boxford, W. E., Pearce, J. K. & Dessent, C. E. H., 1 Dec 2004, In: Chemical Physics Letters. 399, 4-6, p. 465-470 6 p.

  Research output: Contribution to journal › Article › peer-review

• Probing the effects of molecular conformation on ionization dynamics using threshold ionization techniques.

  Dessent, C. E. H., Ford, M. S., Tong, X. & Muller-Dethlefs, K., 28 Mar 2004, In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 227, p. U246-U246 1 p.

  Research output: Contribution to journal › Article › peer-review

• 2003

  Exploring the microscopic solvation of doubly charged anions: symmetric or asymmetric solvation in the CO2-(CH2)(4)-CO22-center dot(H2O)(2) dicarboxylate dianion cluster?

  Dessent, C. E. H. & Rigby, C., 7 Mar 2003, In: Chemical Physics Letters. 370, 1-2, p. 52-61 10 p.

  Research output: Contribution to journal › Article › peer-review

• The effect of conformation on the ionization energetics of n-butylbenzene. I. A threshold ionization study

  Tong, X., Ford, M. S., Dessent, C. E. H. & Muller-Dethlefs, K., 22 Dec 2003, In: Journal of Chemical Physics. 119, 24, p. 12908-12913 6 p.

  Research output: Contribution to journal › Article › peer-review

• The effect of conformation on the ionization energetics of n-butylbenzene. II. A zero electron kinetic energy photoelectron spectroscopy study with partial rotational resolution

  Ford, M. S., Tong, X., Dessent, C. E. H. & Muller-Dethlefs, K., 22 Dec 2003, In: Journal of Chemical Physics. 119, 24, p. 12914-12920 7 p.

  Research output: Contribution to journal › Article › peer-review
• 2002

  A PW91 density functional study of conformational choice in 2-phenylethanol, n-butylbenzene, and their cations: Problems for density functional theory?

  Patey, M. D. & Dessent, C. E. H., Apr 2002, In: Journal of Physical Chemistry A. 106, 18, p. 4623-4631 8 p.

  Research output: Contribution to journal › Article › peer-review

• A REMPI and ZEKE spectroscopic study of the trans-formanilide center dot Ar van der Walls cluster

  Ullrich, S., Tarczay, G., Tong, X., Ford, M. S., Dessent, C. E. H. & Muller-Dethlefs, K., 4 Jan 2002, In: Chemical Physics Letters. 351, 1-2, p. 121-127 7 p.

  Research output: Contribution to journal › Article › peer-review

• Hydration of a cationic amide group: a ZEKE spectroscopic study of trans-formanilide H2O

  Ullrich, S., Tong, X., Tarczay, G., Dessent, C. E. H. & Muller-Dethlefs, K., 2002, In: Physical Chemistry Chemical Physics. 4, 13, p. 2897-2903 7 p.

  Research output: Contribution to journal › Article › peer-review

• Intermolecular vibration and internal rotation of a methyl group in acetanilide Ar: a ZEKE photoelectron spectroscopy study

  Tong, X., Ullrich, S., Dessent, C. E. H. & Muller-Dethlefs, K., 2002, In: Physical Chemistry Chemical Physics. 4, 15, p. 3578-3582 5 p.

  Research output: Contribution to journal › Article › peer-review

• The PFI-ZEKE photoelectron spectrum of m-fluorophenol and its aqueous complexes: Comparing intermolecular vibrations in rotational isomers

  Yosida, K., Suzuki, K., Ishiuchi, S., Sakai, M., Fujii, M., Dessent, C. E. H. & Muller-Dethlefs, K., 2002, In: Physical Chemistry Chemical Physics. 4, 12, p. 2534-2538 5 p.

  Research output: Contribution to journal › Article › peer-review

• ZEKE photoelectron spectroscopy of the cis and trans isomers of formanilide

  Ullrich, S., Tarczay, G., Tong, X., Dessent, C. E. H. & Muller-Dethlefs, K., 2002, In: Angewandte Chemie International Edition. 41, 1, p. 166-168 3 p.

  Research output: Contribution to journal › Article › peer-review

• 2001

  A ZEKE photoelectron spectroscopy and ab initio study of the cis- and trans-isomers of formanilide: Characterizing the cationic amide bond?

  Ullrich, S., Tarczay, G., Tong, X., Dessent, C. E. H. & Muller-Dethlefs, K., 15 Dec 2001, In: Physical Chemistry Chemical Physics. 3, 24, p. 5450-5458 9 p.

  Research output: Contribution to journal › Article › peer-review

• 2000

  A density functional theory study of the anthracene anion

  Dessent, C. E. H., 3 Nov 2000, In: Chemical Physics Letters. 330, 1-2, p. 180-187 8 p.

  Research output: Contribution to journal › Article › peer-review

• Ionization-induced conformational changes: REMPI and ZEKE spectroscopy of salicyl and benzyl alcohol

  Dessent, C. E. H., Geppert, W. D., Ullrich, S. & Muller-Dethlefs, K., 17 Mar 2000, In: Chemical Physics Letters. 319, 3-4, p. 375-384 10 p.

  Research output: Contribution to journal › Article › peer-review

• Is the phenol·Ar complex van der Waals or hydrogen-bonded? A REMPI and ZEKE spectroscopic study

  Haines, S. R., Dessent, C. E. H. & Müller-Dethlefs, K., 1 Jan 2000, In: JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA. 108, 1, p. 1-11 11 p.

  Research output: Contribution to journal › Article › peer-review

• Is the phenol center dot Ar complex van der Waals or hydrogen-bonded? A REMPI and ZEKE spectroscopic study

  Haines, S. R., Dessent, C. E. H. & Muller-Dethlefs, K., Jul 2000, In: JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA. 108, 1-3, p. 111 11 p.

  Research output: Contribution to journal › Article › peer-review

• Observation of rotational isomers I: A ZEKE and hole-burning spectroscopy study of 3-methoxyphenol

  Ullrich, S., Geppert, W. D., Dessent, C. E. H. & Muller-Dethlefs, K., 28 Dec 2000, In: Journal of Physical Chemistry A. 104, 51, p. 11864-11869 6 p.

  Research output: Contribution to journal › Article › peer-review

• Observation of rotational isomers II: A ZEKE and hole-burning spectroscopy study of hydrogen-bonded 3-methoxyphenol center dot water clusters

  Geppert, W. D., Ullrich, S., Dessent, C. E. H. & Muller-Dethlefs, K., 28 Dec 2000, In: Journal of Physical Chemistry A. 104, 51, p. 11870-11876 7 p.

  Research output: Contribution to journal › Article › peer-review

• Rotational band contour analysis in REMPI and ZEKE spectroscopy: elucidating the structures of phenol center dot X (X=N-2, CO and Ar) complexes

  Ford, M. S., Haines, S. R., Pugliesi, I., Dessent, C. E. H. & Muller-Dethlefs, K., Nov 2000, In: JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA. 112, 1-3, p. 231-239 9 p.

  Research output: Contribution to journal › Article › peer-review

• Spectroscopic observation of vibrational Feshbach resonances in near-threshold photoexcitation of X^-·CH₃NO₂ (X^- = I^- and Br^-)

  Dessent, C. E. H., Kim, J. & Johnson, M. A., 1 Jan 2000, In: FARADAY DISCUSSIONS. 115, p. 395-406 12 p.

  Research output: Contribution to journal › Article › peer-review

• Spectroscopic observation of vibrational Feshbach resonances in near-threshold photoexcitation of X-center dot CH3NO2 (X- = I- and Br-)

  Dessent, C. E. H., Kim, J. & Johnson, M. A., 2000, In: FARADAY DISCUSSIONS. 115, p. 395-406 12 p.

  Research output: Contribution to journal › Article › peer-review

• 1999

  A new detection scheme for synchronous, high resolution ZEKE and MATI spectroscopy demonstrated on the Phenol center dot Ar complex

  Dessent, C. E. H., Haines, S. R. & Muller-Dethlefs, K., 17 Dec 1999, In: Chemical Physics Letters. 315, 1-2, p. 103-108 6 p.

  Research output: Contribution to journal › Article › peer-review

• Evidence for stable Rydberg states in the presence of an electron scavenger: The ZEKE spectrum of the toluene·SF₆ complex

  Geppert, W. D., Dessent, C. E. H., Cockett, M. C. R. & Müller-Dethlefs, K., 2 Apr 1999, In: Chemical Physics Letters. 303, 1-2, p. 194-200 7 p.

  Research output: Contribution to journal › Article › peer-review

• Evidence for stable Rydberg states in the presence of an electron scavenger: The ZEKE spectrum of the toluene center dot SF6 complex

  Geppert, W. D., Dessent, C. E. H., Cockett, M. C. R. & Muller-Dethlefs, K., 2 Apr 1999, In: Chemical Physics Letters. 303, 1-2, p. 194-200 7 p.

  Research output: Contribution to journal › Article › peer-review

• Mass analyzed threshold ionization of phenol center dot CO: Intermolecular binding energies of a hydrogen-bonded complex

  Haines, S. R., Dessent, C. E. H. & Muller-Dethlefs, K., 1 Aug 1999, In: Journal of Chemical Physics. 111, 5, p. 1947-1954 8 p.

  Research output: Contribution to journal › Article › peer-review

• Observation of hydrogen-bonded rotational isomers of the resorcinol water complex

  Geppert, W. D., Dessent, C. E. H., Ullrich, S. & Muller-Dethlefs, K., 9 Sept 1999, In: Journal of Physical Chemistry A. 103, 36, p. 7186-7191 6 p.

  Research output: Contribution to journal › Article › peer-review

• ZEKE and hole-burning spectroscopy of the rotational isomers of resorcinol center dot CO

  Geppert, W. D., Dessent, C. E. H. & Muller-Dethlefs, K., 2 Dec 1999, In: Journal of Physical Chemistry A. 103, 48, p. 9687-9692 6 p.

  Research output: Contribution to journal › Article › peer-review

• 1998

  Evidence for a strong intermolecular bond in the phenol center dot N-2 cation

  Haines, S. R., Geppert, W. D., Chapman, D. M., Watkins, M. J., Dessent, C. E. H., Cockett, M. C. R. & Muller-Dethlefs, K., 1 Dec 1998, In: Journal of Chemical Physics. 109, 21, p. 9244-9251 8 p.

  Research output: Contribution to journal › Article › peer-review

• Evidence for a strong intermolecular bond in the phenolṡN₂ cation

  Haines, S. R., Geppert, W. D., Chapman, D. M., Watkins, M. J., Dessent, C. E. H., Cockett, M. C. R. & Müller-Dethlefs, K., 1 Dec 1998, In: Journal of Chemical Physics. 109, 21, p. 9244-9251 8 p.

  Research output: Contribution to journal › Article › peer-review
• 1997

  Characterization of the anionic intracluster polymerization reaction product of 2-chloroacrylonitrile trimers by photoelectron spectroscopy

  Tsukuda, T., Kondow, T., Dessent, C. E. H., Bailey, C. G., Johnson, M. A., Hendricks, J. H., Lyapustina, S. A. & Bowen, K. H., 25 Apr 1997, In: Chemical Physics Letters. 269, 1-2, p. 17-21 5 p.

  Research output: Contribution to journal › Article › peer-review

• Photoinitiation of gas-phase S(N)2 reactions through the Evans-Polanyi excited state surface

  Dessent, C. E. H. & Johnson, M. A., 28 May 1997, In: Journal of the American Chemical Society. 119, 21, p. 5067-5068 2 p.

  Research output: Contribution to journal › Article › peer-review

• Vibrational predissociation spectra of I-center dot(H2O): Isotopic labels and weakly bound complexes with Ar and N-2

  Bailey, C. G., Kim, J., Dessent, C. E. H. & Johnson, M. A., 25 Apr 1997, In: Chemical Physics Letters. 269, 1-2, p. 122-127 6 p.

  Research output: Contribution to journal › Article › peer-review

• 1996

  On the vibrational fine structure in the near-threshold photofragmentation spectrum of the I-center dot CH3I complex: Spectroscopic observation of nonadiabatic effects in electron-molecule scattering

  Dessent, C. E. H., Bailey, C. G. & Johnson, M. A., 15 Dec 1996, In: Journal of Chemical Physics. 105, 23, p. 10416-10423 8 p.

  Research output: Contribution to journal › Article › peer-review

• Photoelectron spectra of the CH3CN- dipole-bound anion: Shape-resonance and other vibronic effects.

  Bailey, C. G., Dessent, C. E. H., Kim, J. & Johnson, M. A., 24 Mar 1996, In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 211, p. 278-PHYS 1 p.

  Research output: Contribution to journal › Article › peer-review

• Precursor of the I-aq(-) charge-transfer-to-solvent (CTTS) band in I-center dot(H2O)(n) clusters

  Serxner, D., Dessent, C. E. H. & Johnson, M. A., 22 Oct 1996, In: Journal of Chemical Physics. 105, 16, p. 7231-7234 4 p.

  Research output: Contribution to journal › Article › peer-review

• Vibronic effects in the photon energy-dependent photoelectron spectra of the CH3CN- dipole-bound anion

  Bailey, C. G., Dessent, C. E. H., Johnson, M. A. & Bowen, K. H., 8 May 1996, In: Journal of Chemical Physics. 104, 18, p. 6976-6983 8 p.

  Research output: Contribution to journal › Article › peer-review

• 1995

  CHARACTERIZATION OF THE 2-CHLOROACRYLONITRILE NEGATIVE-ION USING PHOTOELECTRON AND PHOTOFRAGMENTATION SPECTROSCOPIES

  ICHIHASHI, M., HIROKAWA, J., TSUKUDA, T., KONDOW, T., DESSENT, C. E. H., BAILEY, C. G., SCARTON, M. G. & JOHNSON, M. A., 9 Feb 1995, In: Journal of Physical Chemistry A. 99, 6, p. 1655-1659 5 p.

  Research output: Contribution to journal › Article › peer-review

• DIPOLE-BOUND EXCITED-STATES OF THE I-CENTER-DOT-CH3CN AND I-CENTER-DOT(CH3CN)(2) ION-MOLECULE COMPLEXES - EVIDENCE FOR ASYMMETRIC SOLVATION

  DESSENT, C. E. H., BAILEY, C. G. & JOHNSON, M. A., 8 Aug 1995, In: Journal of Chemical Physics. 103, 6, p. 2006-2015 10 p.

  Research output: Contribution to journal › Article › peer-review

• PHOTOINITIATION OF THE ANIONIC CONDENSATION REACTION IN 2-CHLOROACRYLONITRILE VIA THE CHARGE-TRANSFER BANDS OF THE CL-CENTER-DOT(2-CHLOROACRYLONITRILE)(1,2) CLUSTERS

  DESSENT, C. E. H., BAILEY, C. G. & JOHNSON, M. A., 29 Sept 1995, In: Chemical Physics Letters. 244, 1-2, p. 127-132 6 p.

  Research output: Contribution to journal › Article › peer-review