Neil Scott

Search results

• 2025

  Catalyst Activation and Speciation Involving DyadPalladate™ Pre-Catalysts in Suzuki-Miyaura and Buchwald-Hartwig Cross-Couplings

  Scott, N., Chirila, P., Horbaczewskyj, C. S., Whitwood, A. C., Slack, E. & Fairlamb, I. J. S., 10 Mar 2025, In: Organometallics. 44, p. 654-664 11 p.

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• 2024

  Evidence for Suzuki-Miyaura cross-couplings catalyzed by ligated Pd₃-clusters: from cradle to grave

  Jeddi, N., Scott, N. W. J., Tanner, T., Beaumont, S. K. & Fairlamb, I. J. S., 15 Jan 2024, In: Chemical Science. 15, 8, p. 2763-2777 15 p.

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• 2023

  Opening a Pandora’s Flask on a Prototype Catalytic Direct Arylation Reaction of Pentafluorobenzene: The Ag₂CO₃/Pd(OAc)₂/PPh₃ System

  Platt, G. M. H., Aguiar, P. M., Athavan, G., Bray, J. T. W., Scott, N. W. J., Fairlamb, I. J. S. & Perutz, R. N., 11 Sept 2023, In: Organometallics. 42, p. 2378-2394 17 p.

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• 2021

  A Dichotomy in Cross-Coupling Site Selectivity in a Dihalogenated Heteroarene: Influence of Mononuclear Pd, Pd Clusters, and Pd Nanoparticles—the Case for Exploiting Pd Catalyst Speciation

  Scott, N., Ford, M. J., Jeddi, N., Eyles, A., Simon, L., Whitwood, A. C., Tanner, T., Willans, C. E. & Fairlamb, I. J. S., 21 Jun 2021, In: Journal of the American Chemical Society. 143, 25, p. 9682-9693 12 p.

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• Bridging the Gap from Mononuclear Pd^IIPrecatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd₃(XPh₃)₄]²⁺Clusters as Catalytic Species for Suzuki-Miyaura Couplings (X = P, As)

  Appleby, K. M., Dzotsi, E., Scott, N. W. J., Dexin, G., Jeddi, N., Whitwood, A. C., Pridmore, N. E., Hart, S., Duckett, S. B. & Fairlamb, I. J. S., 8 Nov 2021, In: Organometallics. 40, 21, p. 3560–3570 11 p.

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• Reactivity of a Dinuclear Pd^IComplex [Pd₂(μ-PPh₂)(μ₂-OAc)(PPh₃)₂] with PPh₃: Implications for Cross-Coupling Catalysis Using the Ubiquitous Pd(OAc)₂/nPPh₃Catalyst System

  Scott, N. W. J., Ford, M. J., Husbands, D. R., Whitwood, A. C. & Fairlamb, I. J. S., 13 Sept 2021, In: Organometallics. 40, 17, p. 2995-3002 8 p.

  Research output: Contribution to journal › Article › peer-review

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• 2019

  The ubiquitous cross-coupling catalyst system ‘Pd(OAc)2’/2PPh3 forms a unique dinuclear PdI complex: an important entry point into catalytically competent cyclic Pd3 clusters

  Scott, N. W. J., Ford, M., Schotes, C., Parker, R. R. & Fairlamb, I. J. S., 14 Sept 2019, In: Chemical Science. p. 1-8 8 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

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