Robin Noel Perutz

Search results

• 2012

  Hydrofluoroarylation of alkynes with Ni catalysts. C-H activation via ligand-to-ligand hydrogen transfer, an alternative to oxidative addition

  Guihaumé, J., Halbert, S., Eisenstein, O. & Perutz, R. N., 27 Feb 2012, In: Organometallics. 31, 4, p. 1300-1314

  Research output: Contribution to journal › Article › peer-review

• Selective Photochemistry at Stereogenic Metal and Ligand Centers of cis-[Ru(diphosphine)2(H)2]: Preparative, NMR, solid state, and laser flash studies

  Câmpian, M. V., Perutz, R. N., Procacci, B., Thatcher, R. J., Torres, O. & Whitwood, A. C., 22 Feb 2012, In: Journal of the American Chemical Society. 134, 7, p. 3480-3497

  Research output: Contribution to journal › Article › peer-review

• Smithson tennant celebration: Tennant's science then and now

  Perutz, R. N., 3 Jul 2012, In: Platinum Metals Review. 56, 3, p. 190-193

  Research output: Contribution to journal › Article › peer-review
• 2011

  C-F and C-H bond activation of fluorobenzenes and fluoropyridines at transition metal centers: How fluorine tips the scales

  Clot, E., Eisenstein, O., Jasim, N., Perutz, R. N., MacGregor, S. A. & McGrady, J. E., 17 May 2011, In: ACCOUNTS OF CHEMICAL RESEARCH. 44, 5, p. 333-348 16 p.

  Research output: Contribution to journal › Article › peer-review

• Energetics of halogen bonding of group 10 metal fluoride complexes

  Beweries, T., Jasim, N. A., Perutz, R. N., Whitwood, A. C., Brammer, L. & McGrady, J. E., 14 Sept 2011, In: Journal of the American Chemical Society. 133, 36, p. 14338-14348 11 p.

  Research output: Contribution to journal › Article › peer-review

• Manganese Alkane Complexes: An IR and NMR Spectroscopic Investigation

  Calladine, J. A., Duckett, S. B., George, M. W., Matthews, S. L., Perutz, R. N., Torres, O. & Vuong, K. Q., 23 Feb 2011, In: Journal of the American Chemical Society. 133, 7, p. 2303-2310 8 p.

  Research output: Contribution to journal › Article › peer-review

• Photo-aquation of cis-[RuCl2(mPTA)(4)](CF3SO3)(4) in water (mPTA = N-methyl-1,3,5-triaza-7-phosphaadamantane)

  Girotti, R., Romerosa, A., Manas, S., Serrano-Ruiz, M. & Perutz, R., 28 Jan 2011, In: Dalton Transactions. 40, 4, p. 828-836 9 p.

  Research output: Contribution to journal › Article › peer-review

• Photochemistry and photophysics of a Pd(II) metalloporphyrin: Re(I) tricarbonyl bipyridine molecular dyad and its activity toward the photoreduction of CO to CO

  Schneider, J., Whitwood, A. C., Perutz, R. N., Vuong, K. Q., Calladine, J. A., Sun, X.-Z. & George, M. W., 5 Dec 2011, In: Inorganic Chemistry. 50, 23, p. 11877-11889 13 p.

  Research output: Contribution to journal › Article › peer-review

• Spectroscopic and Structural Investigations Reveal the Signaling Mechanism of a Luminescent Molybdate Sensor

  Corden, V. A., Duhme-Klair, A.-K., Hostachy, S., Perutz, R. N. & Reddig, N., 7 Feb 2011, In: Inorganic Chemistry. 50, 3, p. 1105-1115 11 p.

  Research output: Contribution to journal › Article › peer-review
• 2010

  Design and synthesis of water soluble (metallo)porphyrins with pendant arms: studies of binding to xanthine oxidase

  Gibson, E. A., Duhme-Klair, A.-K. & Perutz, R. N., 2010, In: NEW JOURNAL OF CHEMISTRY. 34, 6, p. 1125-1134 10 p.

  Research output: Contribution to journal › Article › peer-review

• From father to sun

  Cote, M. & Perutz, R., Apr 2010, In: CHEMISTRY WORLD. 7, 4, p. 35-35 1 p.

  Research output: Contribution to journal › Editorial › peer-review

• Importance of palladium-carbon bond energies in direct arylation of polyfluorinated benzenes

  Guihaume, J., Clot, E., Eisenstein, O. & Perutz, R. N., 21 Nov 2010, In: Dalton Transactions. 39, 43, p. 10510-10519 10 p.

  Research output: Contribution to journal › Article › peer-review

• Liquid injection field desorption/ionization of transition metal fluoride complexes

  Dransfield, T. A., Nazir, R., Perutz, R. N. & Whitwood, A. C., Nov 2010, In: JOURNAL OF FLUORINE CHEMISTRY. 131, 11, p. 1213-1217 5 p.

  Research output: Contribution to journal › Article › peer-review

• Photoinduced N-2 loss as a route to long-lived organometallic alkane complexes: A time-resolved IR and NMR study

  Calladine, J. A., Torres, O., Anstey, M., Ball, G. E., Bergman, R. G., Curley, J., Duckett, S. B., George, M. W., Gilson, A. I., Lawes, D. J., Perutz, R. N., Sun, X.-Z. & Vollhardt, K. P. C., Nov 2010, In: Chemical Science. 1, 5, p. 622-630 9 p.

  Research output: Contribution to journal › Article › peer-review

• Selective Activation of the ortho C-F Bond in Pentafluoropyridine by Zerovalent Nickel: Reaction via a Metallophosphorane Intermediate Stabilized by Neighboring Group Assistance from the Pyridyl Nitrogen

  Nova, A., Reinhold, M., Perutz, R. N., Macgregor, S. A. & McGrady, J. E., 12 Apr 2010, In: Organometallics. 29, 7, p. 1824-1831 8 p.

  Research output: Contribution to journal › Article › peer-review
• 2009

  A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)(2)(cyclopentane)

  Duckett, S. B., George, M. W., Jina, O. S., Matthews, S. L., Perutz, R. N., Sun, X.-Z. & Vuong, K. Q., 2009, In: Chemical Communications. 11, p. 1401-1403 3 p.

  Research output: Contribution to journal › Article › peer-review

• Exceptional Sensitivity of Metal-Aryl Bond Energies to ortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M-C/H-C Bond Energy Correlations

  Clot, E., Megret, C., Eisenstein, O. & Perutz, R. N., 10 Jun 2009, In: Journal of the American Chemical Society. 131, 22, p. 7817-7827 11 p.

  Research output: Contribution to journal › Article › peer-review

• Reactivity, Structures, and NMR Spectroscopy of Half-Sandwich Pentamethylcyclopentadienyl Rhodium Amido Complexes Relevant to Transfer Hydrogenation

  Blacker, A. J., Duckett, S. B., Grace, J., Perutz, R. N. & Whitwood, A. C., 9 Mar 2009, In: Organometallics. 28, 5, p. 1435-1446 12 p.

  Research output: Contribution to journal › Article › peer-review

• Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta(5):eta(1)-C5Me4CH2PPh2)Re(CO)(2)

  Godoy, F., Klahn, A. H., Oelckers, B., Garland, M. T., Ibanez, A. & Perutz, R. N., 2009, In: Dalton Transactions. 16, p. 3044-3051 8 p.

  Research output: Contribution to journal › Article › peer-review

• Synthesis and structure of "16-electron" rhodium(III) catalysts for transfer hydrogenation of a cyclic imine: mechanistic implications

  Blacker, A. J., Clot, E., Duckett, S. B., Eisenstein, O., Grace, J., Nova, A., Perutz, R. N., Taylor, D. J. & Whitwood, A. C., 2009, In: Chemical Communications. 44, p. 6801-6803 3 p.

  Research output: Contribution to journal › Article › peer-review

• Visible-Light Photoisomerization and Photoaquation of trans-[Ru(1,3,5-triaza-7-phosphaadamantane)(4)Cl-2] in Organic Solvent and Water

  Girotti, R., Romerosa, A., Manas, S., Serrano-Ruiz, M. & Perutz, R. N., 20 Apr 2009, In: Inorganic Chemistry. 48, 8, p. 3692-3698 7 p.

  Research output: Contribution to journal › Article › peer-review
• 2008

  Chemistry - A catalytic foothold for fluorocarbon reactions

  Perutz, R. N., 29 Aug 2008, In: Science. 321, 5893, p. 1168-1169 2 p.

  Research output: Contribution to journal › Editorial › peer-review

• Competing C-F Activation Pathways in the Reaction of Pt(0) with Fluoropyridines: Phosphine-Assistance versus Oxidative Addition

  Nova, A., Erhardt, S., Jasim, N. A., Perutz, R. N., Macgregor, S. A., McGrady, J. E. & Whitwood, A. C., 19 Nov 2008, In: Journal of the American Chemical Society. 130, 46, p. 15499-15511 13 p.

  Research output: Contribution to journal › Article › peer-review

• Kelvin corrections

  Perutz, R. N., Feb 2008, In: CHEMISTRY WORLD. 5, 2, p. 36-36 1 p.

  Research output: Contribution to journal › Letter › peer-review

• Metal fluorides form strong hydrogen bonds and halogen bonds: measuring interaction enthalpies and entropies in solution

  Libri, S., Jasim, N. A., Perutz, R. N. & Brammer, L., 25 Jun 2008, In: Journal of the American Chemical Society. 130, 25, p. 7842-7844

  Research output: Contribution to journal › Article › peer-review

• Remote site photosubstitution in metalloporphyrin-rhenium tricarbonylbipyridine assemblies: photo-reactions of molecules with very short lived excited states

  Gabrielsson, A., Smith, J. R. L. & Perutz, R. N., 2008, In: Dalton Transactions. 32, p. 4259-4269 11 p.

  Research output: Contribution to journal › Article › peer-review

• Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: A sigma-borane complex as transition state for isomerization

  Campian, M. V., Clot, E., Eisenstein, O., Helmstedt, U., Jasim, N., Perutz, R. N., Whitwood, A. C. & Williamson, D., 2 Apr 2008, In: Journal of the American Chemical Society. 130, 13, p. 4375-4385 11 p.

  Research output: Contribution to journal › Article › peer-review
• 2007

  Hydrogen Bonding and Wavelength Dependence in Time-resolved Infrared Spectroscopy of Selective Ion-sensors

  Duhme-Klair, A., Perutz, R. N., Reddig, N., Ronayne, K. & Towrie, M., 2007, Rutherford Appleton Laboratory Annual Report 2006/2007. p. 138-139

  Research output: Chapter in Book/Report/Conference proceeding › Chapter

• INOR 724-Improving the sulfur and coke tolerance of Ni cermet materials

  Perutz, R. N. & Sabo-Etienne, S., 25 Mar 2007, In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 233, p. 593-593 1 p.

  Research output: Contribution to journal › Article › peer-review

• Low temperature in situ UV irradiation of [(eta(5)-C5H5)Co(C2H4)(2)] in the NMR probe: formation of Co(III) silyl hydride complexes

  Ampt, K. A. M., Duckett, S. B. & Perutz, R. N., 2007, In: Dalton Transactions. 28, p. 2993-2996 4 p.

  Research output: Contribution to journal › Article › peer-review

• Sequential C-F activation and borylation of fluoropyridines via intermediate Rh(I) fluoropyridyl complexes: a multinuclear NMR investigation

  Lindup, R. J., Marder, T. B., Perutz, R. N. & Whitwood, A. C., 2007, In: Chemical Communications. 35, p. 3664-3666 3 p.

  Research output: Contribution to journal › Article › peer-review

• The sigma-CAM mechanism: sigma complexes as the basis of sigma-bond metathesis at late-transition-metal centers

  Perutz, R. N. & Sabo-Etienne, S., 2007, In: Angewandte Chemie International Edition. 46, 15, p. 2578-2592 15 p.

  Research output: Contribution to journal › Literature review › peer-review
• 2006

  Comparisons of photoinduced oxidative addition of B-H, B-B, and Si-H bonds at rhodium(eta(5)-cyclopentadienyl)phosphine centers

  Campian, M. V., Harris, J. L., Jasim, N., Perutz, R. N., Marder, T. B. & Whitwood, A. C., 9 Oct 2006, In: Organometallics. 25, 21, p. 5093-5104 12 p.

  Research output: Contribution to journal › Article › peer-review

• Ir-catalyzed borylation of C-H bonds in N-containing heterocycles: Regioselectivity in the synthesis of heteroaryl boronate esters

  Mkhalid, I. A. I., Coventry, D. N., Albesa-Jove, D., Batsanov, A. S., Howard, J. A. K., Perutz, R. N. & Marder, T. B., 2006, In: Angewandte Chemie International Edition. 45, 3, p. 489-491 3 p.

  Research output: Contribution to journal › Article › peer-review

• Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: In situ photolysis, parahydrogen, and computational studies

  Ampt, K. A. M., Burling, S., Donald, S. M. A., Douglas, S., Duckett, S. B., Macgregor, S. A., Perutz, R. N. & Whittlesey, M. K., 14 Jun 2006, In: Journal of the American Chemical Society. 128, 23, p. 7452-7453 2 p.

  Research output: Contribution to journal › Article › peer-review

• Transition metal- mediated C-F bond activation

  Braun, T. & Perutz, R. N., 2006, Comprehensive Organometallic Chemistry III. Crabtree, R. & Mingos, D. (eds.). Oxford: Elsevier

  Research output: Chapter in Book/Report/Conference proceeding › Chapter

• Ultrafast charge separation in a photoreactive rhenium-appended porphyrin assembly monitored by picosecond transient infrared spectroscopy

  Gabrielsson, A., Hartl, F., Zhang, H., Smith, J. R. L., Towrie, M., Vlcek, A. & Perutz, R. N., 5 Apr 2006, In: Journal of the American Chemical Society. 128, 13, p. 4253-4266 14 p.

  Research output: Contribution to journal › Article › peer-review

• Validation of the M-C/H-C bond enthalpy relationship through application of density functional theory

  Clot, E., Megret, C., Eisenstein, O. & Perutz, R. N., 28 Jun 2006, In: Journal of the American Chemical Society. 128, 25, p. 8350-8357 8 p.

  Research output: Contribution to journal › Article › peer-review
• 2005

  A metal-based lumophore tailored to sense biologically relevant oxometalates

  Peacock, A. F. A., Raendler, C., Perutz, R. N., Duhme-Klair, A. K., Batey, H. D. & Whitwood, A. C., Mar 2005, In: Angewandte Chemie International Edition. 44, 11, p. 1712-1714 2 p.

  Research output: Contribution to journal › Article › peer-review

• C-F Bond activation at Ni(0) and simple reactions of square planar Ni(II) fluoride complexes

  Burling, S., Elliott, P. I. P., Jasim, N. A., Lindup, R. J., McKenna, J., Perutz, R. N., Archibald, S. J. & Whitwood, A. C., 2005, In: Dalton Transactions. 22, p. 3686-3695 10 p.

  Research output: Contribution to journal › Article › peer-review

• Photochemical reactions of (eta(5)-cyclopentadienyl)bis(t-butylacrylate) rhodium with silanes: Dynamics of isomer interconversion via Rh(eta(2)-silane) species (pg 3331, 2004)

  Ampt, K. A. M., Duckett, S. B. & Perutz, R. N., 2005, In: Dalton Transactions. 7, p. 1319-1319 1 p.

  Research output: Contribution to journal › Article › peer-review

• Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters

  Coventry, D. N., Batsanov, A. S., Goeta, A. E., Howard, J. A. K., Marder, T. B. & Perutz, R. N., 2005, In: Chemical Communications. 16, p. 2172-2174 3 p.

  Research output: Contribution to journal › Article › peer-review
• 2004

  A comparison of C-F and C-H bond activation by zerovalent Ni and Pt: a density functional study

  Reinhold, M., Perutz, R. N. & McGrady, J. E., 28 Apr 2004, In: Journal of the American Chemical Society. 126, 16, p. 5268-5276 8 p.

  Research output: Contribution to journal › Article › peer-review

• Contrasting reactivity of fluoropyridines at palladium and platinum: C-F oxidative addition at palladium, P-C and C-F activation at platinum

  Jasim, N. A., Perutz, R. N., Whitwood, A. C., Braun, T., Izundu, J., Neumann, B., Rothfeld, S. & Stammler, H. G., 20 Dec 2004, In: Organometallics. 23, 26, p. 6140-6149 10 p.

  Research output: Contribution to journal › Article › peer-review

• Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(I)

  Duckett, S. B., Galvez-Lopez, M. D., Perutz, R. N. & Schott, D., 2004, In: Dalton Transactions. 17, p. 2746-2749 4 p.

  Research output: Contribution to journal › Article › peer-review

• Light-controlled ion switching: Direct observation of the complete nanosecond release and microsecond recapture cycle of an azacrown-substituted [(bpy)Re(CO)₃L]⁺ complex

  Lewis, J. D., Perutz, R. N. & Moore, J. N., 21 Oct 2004, In: Journal of Physical Chemistry A. 108, 42, p. 9037-9047 11 p.

  Research output: Contribution to journal › Article › peer-review

• Photochemical oxidative addition of B-H bonds at ruthenium and rhodium

  Callaghan, P. L., Fernandez-Pacheco, R., Jasim, N., Lachaize, S., Marder, T. B., Perutz, R. N., Rivalta, E. & Sabo-Etienne, S., 21 Jan 2004, In: Chemical Communications. 2, p. 242-243 2 p.

  Research output: Contribution to journal › Article › peer-review

• Photochemical reactions of (eta(5)-cyclopentadienyl)bis(t-butylacrylate) rhodium with silanes: Dynamics of isomer interconversion via Rh(eta 2-silane) species

  Ampt, K. A. M., Duckett, S. B. & Perutz, R. N., 2004, In: Dalton Transactions. 20, p. 3331-3337 7 p.

  Research output: Contribution to journal › Article › peer-review

• Photochemistry of Ru(etp)(CO)H-2 (etp = PhP(CH2CH2PPh2)(2)): Fast oxidative addition and coordination following exclusive dihydrogen loss

  Montiel-Palma, V., Pattison, D. I., Perutz, R. N. & Turner, C., 16 Aug 2004, In: Organometallics. 23, 17, p. 4034-4039 6 p.

  Research output: Contribution to journal › Article › peer-review

• Platinum bis(tricyclohexylphosphine) silyl hydride complexes

  Chan, D., Duckett, S. B., Heath, S. L., Khazal, I. G., Perutz, R. N., Sabo-Etienne, S. & Timmins, P. L., 22 Nov 2004, In: Organometallics. 23, 24, p. 5744-5756 13 p.

  Research output: Contribution to journal › Article › peer-review