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19F mas NMR and FTIR analysis of the adsorption of alkali metal fluorides onto alumina
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| Journal | Journal of molecular catalysis |
|---|---|
| Date | Published - 15 Oct 1990 |
| Issue number | 2 |
| Volume | 62 |
| Number of pages | 10 |
| Pages (from-to) | 233-242 |
| Original language | English |
Abstract
NaF, KF, RbF and CsF have been adsorbed onto alumina and the resulting reagents have been analysed by IR and 19F magic-angle spinning NMR spectroscopy. The results show that MF reacts with the alumina surface to form AlF6 3-, and CO3 2- is formed as a byproduct due to the adsorption and reaction of atmospheric CO2.
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