4,4'-DICHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL AND 4-CHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDES AND SULFONES

J H  CLARK; J E  DENNESS; A J  WYND

4,4'-DICHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL AND 4-CHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDES AND SULFONES

J H CLARK, J E DENNESS, A J WYND

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

4,4'-Dichloro-2,2'-bis(trifluoromethyl)diphenyl sulphoxide can be prepared from 2-bromo-4-chlorobenzotrifluoride and converted to the 2,2'-bis(trifluoromethyl)diphenyl sulphone, although the oxidation is remarkably difficult owing to the steric protection of the lone pair on sulphur by the two CF3 groups. Both the sulphoxide and the sulphone can be converted into the 4-chloro-4'-hydroxy single monomers.

Original language	English
Pages (from-to)	249-251
Number of pages	3
Journal	JOURNAL OF FLUORINE CHEMISTRY
Volume	69
Issue number	3
Publication status	Published - Dec 1994

Keywords

DICHLORO-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDE BIS(TRIFLUOROMETHYL)DIPHENYL SULFONE
NMR SPECTROSCOPY
IR SPECTROSCOPY
CRYSTAL STRUCTURE DETERMINATION
MASS SPECTROMETRY

Cite this

@article{209f2362a0734d4c997fcae41aee8940,

title = "4,4'-DICHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL AND 4-CHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDES AND SULFONES",

abstract = "4,4'-Dichloro-2,2'-bis(trifluoromethyl)diphenyl sulphoxide can be prepared from 2-bromo-4-chlorobenzotrifluoride and converted to the 2,2'-bis(trifluoromethyl)diphenyl sulphone, although the oxidation is remarkably difficult owing to the steric protection of the lone pair on sulphur by the two CF3 groups. Both the sulphoxide and the sulphone can be converted into the 4-chloro-4'-hydroxy single monomers.",

keywords = "DICHLORO-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDE BIS(TRIFLUOROMETHYL)DIPHENYL SULFONE, NMR SPECTROSCOPY, IR SPECTROSCOPY, CRYSTAL STRUCTURE DETERMINATION, MASS SPECTROMETRY",

author = "CLARK, {J H} and DENNESS, {J E} and WYND, {A J}",

year = "1994",

month = dec,

language = "English",

volume = "69",

pages = "249--251",

journal = "JOURNAL OF FLUORINE CHEMISTRY",

issn = "0022-1139",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - 4,4'-DICHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL AND 4-CHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDES AND SULFONES

AU - CLARK, J H

AU - DENNESS, J E

AU - WYND, A J

PY - 1994/12

Y1 - 1994/12

N2 - 4,4'-Dichloro-2,2'-bis(trifluoromethyl)diphenyl sulphoxide can be prepared from 2-bromo-4-chlorobenzotrifluoride and converted to the 2,2'-bis(trifluoromethyl)diphenyl sulphone, although the oxidation is remarkably difficult owing to the steric protection of the lone pair on sulphur by the two CF3 groups. Both the sulphoxide and the sulphone can be converted into the 4-chloro-4'-hydroxy single monomers.

AB - 4,4'-Dichloro-2,2'-bis(trifluoromethyl)diphenyl sulphoxide can be prepared from 2-bromo-4-chlorobenzotrifluoride and converted to the 2,2'-bis(trifluoromethyl)diphenyl sulphone, although the oxidation is remarkably difficult owing to the steric protection of the lone pair on sulphur by the two CF3 groups. Both the sulphoxide and the sulphone can be converted into the 4-chloro-4'-hydroxy single monomers.

KW - DICHLORO-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDE BIS(TRIFLUOROMETHYL)DIPHENYL SULFONE

KW - NMR SPECTROSCOPY

KW - IR SPECTROSCOPY

KW - CRYSTAL STRUCTURE DETERMINATION

KW - MASS SPECTROMETRY

M3 - Article

SN - 0022-1139

VL - 69

SP - 249

EP - 251

JO - JOURNAL OF FLUORINE CHEMISTRY

JF - JOURNAL OF FLUORINE CHEMISTRY

IS - 3

ER -