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4,4'-DICHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL AND 4-CHLORO-4'-HYDROXY-2,2'-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDES AND SULFONES

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Publication details

JournalJOURNAL OF FLUORINE CHEMISTRY
DatePublished - Dec 1994
Issue number3
Volume69
Number of pages3
Pages (from-to)249-251
Original languageEnglish

Abstract

4,4'-Dichloro-2,2'-bis(trifluoromethyl)diphenyl sulphoxide can be prepared from 2-bromo-4-chlorobenzotrifluoride and converted to the 2,2'-bis(trifluoromethyl)diphenyl sulphone, although the oxidation is remarkably difficult owing to the steric protection of the lone pair on sulphur by the two CF3 groups. Both the sulphoxide and the sulphone can be converted into the 4-chloro-4'-hydroxy single monomers.

    Research areas

  • DICHLORO-BIS(TRIFLUOROMETHYL)DIPHENYL SULFOXIDE BIS(TRIFLUOROMETHYL)DIPHENYL SULFONE, NMR SPECTROSCOPY, IR SPECTROSCOPY, CRYSTAL STRUCTURE DETERMINATION, MASS SPECTROMETRY

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