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A bipyridyl palladium complex covalently anchored onto silica as an effective and recoverable interphase catalyst for the aerobic oxidation of alcohols

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A bipyridyl palladium complex covalently anchored onto silica as an effective and recoverable interphase catalyst for the aerobic oxidation of alcohols. / Karimi, B ; Zamani, A ; Clark, J H .

In: Organometallics, Vol. 24, No. 19, 12.09.2005, p. 4695-4698.

Research output: Contribution to journalArticle

Harvard

Karimi, B, Zamani, A & Clark, JH 2005, 'A bipyridyl palladium complex covalently anchored onto silica as an effective and recoverable interphase catalyst for the aerobic oxidation of alcohols', Organometallics, vol. 24, no. 19, pp. 4695-4698. https://doi.org/10.1021/om050326m

APA

Karimi, B., Zamani, A., & Clark, J. H. (2005). A bipyridyl palladium complex covalently anchored onto silica as an effective and recoverable interphase catalyst for the aerobic oxidation of alcohols. Organometallics, 24(19), 4695-4698. https://doi.org/10.1021/om050326m

Vancouver

Karimi B, Zamani A, Clark JH. A bipyridyl palladium complex covalently anchored onto silica as an effective and recoverable interphase catalyst for the aerobic oxidation of alcohols. Organometallics. 2005 Sep 12;24(19):4695-4698. https://doi.org/10.1021/om050326m

Author

Karimi, B ; Zamani, A ; Clark, J H . / A bipyridyl palladium complex covalently anchored onto silica as an effective and recoverable interphase catalyst for the aerobic oxidation of alcohols. In: Organometallics. 2005 ; Vol. 24, No. 19. pp. 4695-4698.

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@article{d896c1fadd0e4b6dad1ce3d24d4e220a,
title = "A bipyridyl palladium complex covalently anchored onto silica as an effective and recoverable interphase catalyst for the aerobic oxidation of alcohols",
abstract = "A new silica-based Pd(II) interphase catalyst 2 efficiently catalyzes the aerobic oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds. The catalyst is also quite effective for the oxidation of primary benzylic alcohols under atmospheric pressure of air. The catalyst shows high thermal stability (up to 200 degrees C) and is also stable under the oxidation reaction conditions. To our knowledge this work is the first example of the application of a palladium complex covalently anchored to silica for the aerobic oxidation of alcohols.",
keywords = "SECONDARY ALCOHOLS, MOLECULAR-OXYGEN, SELECTIVE OXIDATION, KINETIC RESOLUTION, PALLADIUM(II)-CATALYZED OXIDATION, ALPHA,BETA-UNSATURATED ALDEHYDES, MECHANISTIC INVESTIGATIONS, ORGANIC TRANSFORMATIONS, HETEROGENEOUS CATALYST, ALLYLIC ALCOHOLS",
author = "B Karimi and A Zamani and Clark, {J H}",
year = "2005",
month = "9",
day = "12",
doi = "10.1021/om050326m",
language = "English",
volume = "24",
pages = "4695--4698",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "19",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - A bipyridyl palladium complex covalently anchored onto silica as an effective and recoverable interphase catalyst for the aerobic oxidation of alcohols

AU - Karimi, B

AU - Zamani, A

AU - Clark, J H

PY - 2005/9/12

Y1 - 2005/9/12

N2 - A new silica-based Pd(II) interphase catalyst 2 efficiently catalyzes the aerobic oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds. The catalyst is also quite effective for the oxidation of primary benzylic alcohols under atmospheric pressure of air. The catalyst shows high thermal stability (up to 200 degrees C) and is also stable under the oxidation reaction conditions. To our knowledge this work is the first example of the application of a palladium complex covalently anchored to silica for the aerobic oxidation of alcohols.

AB - A new silica-based Pd(II) interphase catalyst 2 efficiently catalyzes the aerobic oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds. The catalyst is also quite effective for the oxidation of primary benzylic alcohols under atmospheric pressure of air. The catalyst shows high thermal stability (up to 200 degrees C) and is also stable under the oxidation reaction conditions. To our knowledge this work is the first example of the application of a palladium complex covalently anchored to silica for the aerobic oxidation of alcohols.

KW - SECONDARY ALCOHOLS

KW - MOLECULAR-OXYGEN

KW - SELECTIVE OXIDATION

KW - KINETIC RESOLUTION

KW - PALLADIUM(II)-CATALYZED OXIDATION

KW - ALPHA,BETA-UNSATURATED ALDEHYDES

KW - MECHANISTIC INVESTIGATIONS

KW - ORGANIC TRANSFORMATIONS

KW - HETEROGENEOUS CATALYST

KW - ALLYLIC ALCOHOLS

U2 - 10.1021/om050326m

DO - 10.1021/om050326m

M3 - Article

VL - 24

SP - 4695

EP - 4698

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 19

ER -