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A bis(imido)organoarsenate dianion incorporating n-butyllithium

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JournalDalton Transactions
DatePublished - 2003
Issue number11
Number of pages2
Pages (from-to)2103-2104
Original languageEnglish

Abstract

Reaction of AsCl3 with 3 equivalents of (2-OPh) C6H4NH2 in toluene/NEt3, followed by metallation with 3 equivalents of (BuLi)-Li-n produces a bis(imido) organoarsenate dianion as a lithium salt which co-complexes (BuLi)-Li-n to form a dimeric cage with a 14 membered core.

    Research areas

  • IMIDO ANALOGS, OXOANIONS, ANIONS

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