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A concise, stereoselective synthesis of meso-2,6-diaminopimelic acid (DAP)

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Publication details

JournalTetrahedron Letters
DatePublished - 20 Aug 2001
Issue number34
Volume42
Number of pages2
Pages (from-to)5953-5954
Original languageEnglish

Abstract

The preparation of meso-2,6-diaminopimelic acid 1 is described. The key step in the synthesis is Suzuki coupling of the novel organoboron homoalanine equivalent 3 with methyl (2Z)-3-bromo-2-[(tert-butoxycarbonyl)amino]-2-propenoate 5. (C) 2001 Elsevier Science Ltd. All rights reserved.

    Research areas

  • ASYMMETRIC-SYNTHESIS, AMINO-ACIDS, DIAMINOPIMELIC ACID, DERIVATIVES, INHIBITORS, LYSINE

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