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A CONCISE SYNTHESIS OF THE NOVEL ANTIBIOTIC ARANOROSIN
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| Journal | Tetrahedron Letters |
|---|---|
| Date | Published - 27 Aug 1993 |
| Issue number | 35 |
| Volume | 34 |
| Number of pages | 4 |
| Pages (from-to) | 5519-5522 |
| Original language | English |
Abstract
A short synthesis of the novel antibiotic aranorosin is described which employs a novel hypervalent iodine-mediated oxidative hydroxylation of a tyrosinal derivative in the key step. A similar procedure was employed to prepare 6'-epiaranorosin, and hence establish the stereochemistry of the natural compound.
- HYPERVALENT IODINE OXIDATION, PSEUDOARACHNIOTUS-ROSEUS, MONOACETALS
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