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A convergent synthesis of the tricyclic core of the dictyosphaeric acids

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JournalOrganic Letters
DatePublished - 17 Jan 2008
Issue number2
Volume10
Number of pages4
Pages (from-to)353-356
Original languageEnglish

Abstract

The first synthetic route to the tricyclic core of the dictyosphaeric acids has been established starting from readily available (S)-(-)-4-(tert-butyldimethylsilyloxy)cyclohexenone and involving 9 steps, including a ring-closing metathesis to produce a 13-membered macrolactone, and a doubly tethered intramolecular Michael addition.

    Research areas

  • MICHAEL REACTION, 4-HYDROXYCYCLOHEX-2-ENONE

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