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A convergent synthesis of the tricyclic core of the dictyosphaeric acids
Research output: Contribution to journal › Article › peer-review
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| Journal | Organic Letters |
|---|---|
| Date | Published - 17 Jan 2008 |
| Issue number | 2 |
| Volume | 10 |
| Number of pages | 4 |
| Pages (from-to) | 353-356 |
| Original language | English |
Abstract
The first synthetic route to the tricyclic core of the dictyosphaeric acids has been established starting from readily available (S)-(-)-4-(tert-butyldimethylsilyloxy)cyclohexenone and involving 9 steps, including a ring-closing metathesis to produce a 13-membered macrolactone, and a doubly tethered intramolecular Michael addition.
- MICHAEL REACTION, 4-HYDROXYCYCLOHEX-2-ENONE
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