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A direct C-H/Ar-H coupling approach to oxindoles, thio-oxindoles, 3,4-dihydro-1H-quinolin-2-ones, and 1,2,3,4-tetrahydroquinolines

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JournalChemistry : A European Journal (Weinheim an der Bergstrasse, Germany)
DateE-pub ahead of print - 11 Sep 2014
DatePublished (current) - 20 Oct 2014
Issue number43
Volume20
Number of pages11
Pages (from-to)14063-14073
Early online date11/09/14
Original languageEnglish

Abstract

A copper(II)-catalysed approach to oxindoles, thio-oxindoles, 3,4-dihydro-1H-quinolin-2-ones, and 1,2,3,4-tetrahydroquinolines via formal C-H, Ar-H coupling is described. In a new variant, copper(II) 2-ethylhexanoate has been identified as an inexpensive and efficient catalyst for this transformation, which utilises atmospheric oxygen as the re-oxidant.

Bibliographical note

© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

    Research areas

  • Catalysis, Copper, Dihydroquinolinones, Oxindoles, Tetrahydroquinolines

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