TY - JOUR
T1 - A fluorine-19 nuclear magnetic resonance study of the strong hydrogen bond between aliphatic diols or acids and alkali-metal fluorides
AU - Miller, Jack M.
AU - Kanippayoor, Ravendran K.
AU - Clark, James H.
PY - 1983/1/1
Y1 - 1983/1/1
N2 - Solutions of alkali metal fluorides in aliphatic diols or carboxylic acids have been investigated by 19F n.m.r. at concentrations of ca. 0.5 mol kg-1 and greater. Heats of association of potassium fluoride with ethane-1,2-diol and methanoic acid are obtained from variable-temperature n.m.r. studies. The nature of the strong hydrogen bond and its influence on the n.m.r. spectra are discussed.
AB - Solutions of alkali metal fluorides in aliphatic diols or carboxylic acids have been investigated by 19F n.m.r. at concentrations of ca. 0.5 mol kg-1 and greater. Heats of association of potassium fluoride with ethane-1,2-diol and methanoic acid are obtained from variable-temperature n.m.r. studies. The nature of the strong hydrogen bond and its influence on the n.m.r. spectra are discussed.
UR - http://www.scopus.com/inward/record.url?scp=0000998030&partnerID=8YFLogxK
U2 - 10.1039/DT9830000683
DO - 10.1039/DT9830000683
M3 - Article
AN - SCOPUS:0000998030
SN - 1472-7773
SP - 683
EP - 687
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 4
ER -