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A fluorine-19 nuclear magnetic resonance study of the strong hydrogen bond between aliphatic diols or acids and alkali-metal fluorides

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JournalJournal of the Chemical Society, Dalton Transactions
DatePublished - 1 Jan 1983
Issue number4
Number of pages5
Pages (from-to)683-687
Original languageEnglish

Abstract

Solutions of alkali metal fluorides in aliphatic diols or carboxylic acids have been investigated by 19F n.m.r. at concentrations of ca. 0.5 mol kg-1 and greater. Heats of association of potassium fluoride with ethane-1,2-diol and methanoic acid are obtained from variable-temperature n.m.r. studies. The nature of the strong hydrogen bond and its influence on the n.m.r. spectra are discussed.

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