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A general route to the Streptomyces-derived inthomycin family: the first synthesis of (+)-inthomycin B

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JournalTetrahedron Letters
DatePublished - 23 Jan 2006
Issue number4
Volume47
Number of pages4
Pages (from-to)549-552
Original languageEnglish

Abstract

94 Abstract-A concise, convergent and stereocontrolled synthesis of (+)-inthornycin B, based on the Stille coupling of a stannyl-diene with an oxazole vinyl iodide unit, is described. The asymmetric centre was introduced using the Kiyooka ketene acetal/amino acid-derived oxazaborolidinone procedure. (c) 2005 Elsevier Ltd. All rights reserved.

    Research areas

  • CELLULOSE BIOSYNTHESIS, BIOLOGICAL-ACTIVITY, MICROBIAL ORIGIN, ALDOL REACTIONS, PHTHOXAZOLIN-A, OXAZOLOMYCIN, ANTIBIOTICS, INHIBITOR, OXAZABOROLIDINONE, NEOOXAZOLOMYCIN

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