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Journal | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS |
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Date | Published - 7 Aug 1993 |
Issue number | 15 |
Number of pages | 2 |
Pages (from-to) | 1224-1225 |
Original language | English |
The radical-mediated cyclisation of serine derived alpha-chloroamides has beer found to be influenced in both yield and stereoselectivity by the nature of the substituent at the site of radical generation-radicals substituted at the alpha-position by methyl, phenyl and dichloro groups underwent smooth cyclisation to give excellent yield of pyrrolidinones in which the trans-C-2 : C-3 isomer predominated-this procedure has potential application to a new synthesis of the kainoid amino acids.
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