Research output: Contribution to journal › Article › peer-review
Journal | Dalton Transactions |
---|---|
Date | Published - 2008 |
Issue number | 34 |
Volume | 37 |
Number of pages | 3 |
Pages (from-to) | 4552-4554 |
Original language | English |
The conversion of the alkyne complex RhCl(PPr3i)(2)(eta(2)-PhC CH) into its vinylidene isomer RhCl(PPr3i)(2)(=C=CPhH) has been monitored via NMR spectroscopy in a range of solvents. In THF and hexane solution the reaction was observed to proceed via the alkynyl hydride complex Rh(H)Cl(PPr3i)(2)(-C=CPh). The kinetic profile of the reaction demonstrates that this species is an intermediate in the formation of the vinylidene complex.
Find related publications, people, projects, datasets and more using interactive charts.