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A mild and selective Pd-mediated methodology for the synthesis of highly fluorescent 2-arylated tryptophans and tryptophan-containing peptides: a catalytic role for Pd(0) nanoparticles?

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JournalChemical Communications
DateE-pub ahead of print - 10 Feb 2014
DatePublished (current) - 2014
Issue number23
Volume50
Number of pages3
Pages (from-to)3052-4
Early online date10/02/14
Original languageEnglish

Abstract

A Pd-mediated direct C-H bond functionalisation of tryptophan has been developed, both as a single amino acid residue and within peptides. Important mechanistic insight into this process has been gained by characterising a Pd catalytically competent nanoparticle phase which evolves during the early stages of reaction.

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