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A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
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Publication details
| Journal | Journal of the American Chemical Society |
|---|---|
| Date | Accepted/In press - 5 Oct 2020 |
| Date | E-pub ahead of print - 14 Oct 2020 |
| Date | Published (current) - 28 Oct 2020 |
| Issue number | 43 |
| Volume | 142 |
| Number of pages | 6 |
| Pages (from-to) | 18330-18335 |
| Early online date | 14/10/20 |
| Original language | English |
Abstract
We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.
Bibliographical note
© 2020, The Author(s).
Projects
Putting Low Coordination into Practice by the Exploration of Metal-sigma-Interactions: Fundamentals, New Catalysts and Catalysis for New Materials
Project: Research project (funded) › Research
Zintl–Ions as Molecular Analogues of Liquid Alloys for C–H Activation
Project: Other project › Project from former institution
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