A new intermediate in spontaneous styrene polymerisation inhibited by 2-nitrophenol

Robert J. Thatcher; Thomas E. Newby; Peter Price; Colin Loyns; Victor Chechik

doi:10.1039/c4ra05443a

A new intermediate in spontaneous styrene polymerisation inhibited by 2-nitrophenol

Robert J. Thatcher, Thomas E. Newby, Peter Price, Colin Loyns, Victor Chechik^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The polymerisation inhibitor, 2-nitrophenol reacts with radicals generated in self-initiated thermal styrene polymerisation to form the unexpected benzoxazine 1. We propose the mechanism for the formation of 1 and show that it is produced by a radical mediated C-H activation.

Original language	English
Pages (from-to)	35131-35136
Number of pages	6
Journal	RSC Advances
Volume	4
Issue number	66
Early online date	29 Jul 2014
DOIs	https://doi.org/10.1039/c4ra05443a
Publication status	Published - 2014

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title = "A new intermediate in spontaneous styrene polymerisation inhibited by 2-nitrophenol",

abstract = "The polymerisation inhibitor, 2-nitrophenol reacts with radicals generated in self-initiated thermal styrene polymerisation to form the unexpected benzoxazine 1. We propose the mechanism for the formation of 1 and show that it is produced by a radical mediated C-H activation.",

author = "Thatcher, {Robert J.} and Newby, {Thomas E.} and Peter Price and Colin Loyns and Victor Chechik",

year = "2014",

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AU - Price, Peter

AU - Loyns, Colin

AU - Chechik, Victor

PY - 2014

Y1 - 2014

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AB - The polymerisation inhibitor, 2-nitrophenol reacts with radicals generated in self-initiated thermal styrene polymerisation to form the unexpected benzoxazine 1. We propose the mechanism for the formation of 1 and show that it is produced by a radical mediated C-H activation.

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U2 - 10.1039/c4ra05443a

DO - 10.1039/c4ra05443a

M3 - Article

AN - SCOPUS:84906542562

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JO - RSC Advances

JF - RSC Advances

IS - 66

ER -

A new intermediate in spontaneous styrene polymerisation inhibited by 2-nitrophenol

Abstract

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