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A new polymorph and two inclusion compounds of 9,9 '-spirobifluorene

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JournalACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
DatePublished - May 2005
Volume61
Number of pages4
Pages (from-to)O328-O331
Original languageEnglish

Abstract

Two new inclusion compounds of 9,9'-spirobifluorene (SBF) incorporating benzene [(I), C25H16• C6H6] and biphenyl [(II), C25H16• C12H10], and a new polymorph of SBF [(III), C25H16] are reported. All three exhibit C-H•••π(arene) hydrogen bonds between adjacent SBF molecules. Compound (II) also contains biphenyl C-H to SBF π-arene interactions. Collectively, hydrogen bonding gives rise to a chain and a layered motif in compounds (I) and (II), respectively.

    Research areas

  • BENZENE, LIQUIDS

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