By the same authors

From the same journal

A new precatalyst for the Suzuki reaction - a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0)

Research output: Contribution to journalArticle

Published copy (DOI)

Author(s)

  • A Beeby
  • S Bettington
  • I J S Fairlamb
  • A E Goeta
  • A R Kapdi
  • E H Niemela
  • A L Thompson

Department/unit(s)

Publication details

JournalNEW JOURNAL OF CHEMISTRY
DatePublished - 2004
Issue number5
Volume28
Number of pages6
Pages (from-to)600-605
Original languageEnglish

Abstract

A dinuclear pyridyl-bridged palladium complex, trans-(P,N)-[PdBr(mu-C5H4N-C-2,N)(PPh3)](2) 1, was obtained from material isolated from the Suzuki cross-coupling reaction of 2-bromopyridine with 2,4-diflorophenylboronic acid in the presence of catalytic (PPh3)(4)Pd. Complex 1 is an effective precatalyst for the Suzuki cross-coupling reactions of a variety organoboronic acids and aryl bromides, and represents a useful source of mono-ligated palladium(0), "(Ph3P)Pd(0)''.

    Research areas

  • CROSS-COUPLING REACTIONS, CAMBRIDGE STRUCTURAL DATABASE, ARYL CHLORIDES, PHENYLBORONIC ACID, CRYSTAL-STRUCTURES, ARYLBORONIC ACIDS, PHASE SYNTHESIS, MILD CONDITIONS, LIGAND, CATALYSIS

Discover related content

Find related publications, people, projects, datasets and more using interactive charts.

View graph of relations