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A new stereocontrolled, pyrylium-based route to conjugated dienynes: The first synthesis of Carduusyne A

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JournalTetrahedron Letters
DatePublished - 11 Mar 1996
Issue number11
Volume37
Number of pages4
Pages (from-to)1913-1916
Original languageEnglish

Abstract

A new stereocontrolled route to conjugated dienynes is described utilising organometallic addition to pyrylium salts followed by Wittig homologation and dehydrohalogenation. The utility of this methodology is illustrated in the first total synthesis of the marine metabolite Carduusyne A.

    Research areas

  • STEREOSELECTIVE SYNTHESIS, ALKYL IODIDES, REAGENTS

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