A NEW TRIPLET BAND SYSTEM OF C-3 - THE APPROXIMATELY-B 3-PI-G-A3-PI-U TRANSITION

H  SASADA; T  AMANO; C  JARMAN; P F  BERNATH

A NEW TRIPLET BAND SYSTEM OF C-3 - THE APPROXIMATELY-B 3-PI-G-A3-PI-U TRANSITION

H SASADA, T AMANO, C JARMAN, P F BERNATH

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A triplet band system of C3 has been observed for the first time in absorption with a distributed-feedback (DFB) diode laser spectrometer and in emission with a Fourier transform spectrometer at around 6500 cm-1. The band has been assigned to the b approximately 3-PI-g-a approximately 3-PI-u system, and the spectroscopic constants in both the upper and lower states have been determined. It is demonstrated that near-infrared DFB lasers are promising radiation sources for spectroscopy of unstable molecules.

Original language	English
Pages (from-to)	2401-2407
Number of pages	7
Journal	Journal of Chemical Physics
Volume	94
Issue number	4
Publication status	Published - 15 Feb 1991

Keywords

FOURIER-TRANSFORM SPECTROSCOPY
JET-COOLED C-3
ELECTRONIC-TRANSITIONS
LASER SPECTROSCOPY
SPECTRUM
C3
MOLECULES
ABINITIO
STATES
C2

Cite this

@article{1c1a98519f49424281b3eb4474839d17,

title = "A NEW TRIPLET BAND SYSTEM OF C-3 - THE APPROXIMATELY-B 3-PI-G-A3-PI-U TRANSITION",

abstract = "A triplet band system of C3 has been observed for the first time in absorption with a distributed-feedback (DFB) diode laser spectrometer and in emission with a Fourier transform spectrometer at around 6500 cm-1. The band has been assigned to the b approximately 3-PI-g-a approximately 3-PI-u system, and the spectroscopic constants in both the upper and lower states have been determined. It is demonstrated that near-infrared DFB lasers are promising radiation sources for spectroscopy of unstable molecules.",

keywords = "FOURIER-TRANSFORM SPECTROSCOPY, JET-COOLED C-3, ELECTRONIC-TRANSITIONS, LASER SPECTROSCOPY, SPECTRUM, C3, MOLECULES, ABINITIO, STATES, C2",

author = "H SASADA and T AMANO and C JARMAN and BERNATH, {P F}",

year = "1991",

month = feb,

day = "15",

language = "English",

volume = "94",

pages = "2401--2407",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "4",

}

TY - JOUR

T1 - A NEW TRIPLET BAND SYSTEM OF C-3 - THE APPROXIMATELY-B 3-PI-G-A3-PI-U TRANSITION

AU - SASADA, H

AU - AMANO, T

AU - JARMAN, C

AU - BERNATH, P F

PY - 1991/2/15

Y1 - 1991/2/15

N2 - A triplet band system of C3 has been observed for the first time in absorption with a distributed-feedback (DFB) diode laser spectrometer and in emission with a Fourier transform spectrometer at around 6500 cm-1. The band has been assigned to the b approximately 3-PI-g-a approximately 3-PI-u system, and the spectroscopic constants in both the upper and lower states have been determined. It is demonstrated that near-infrared DFB lasers are promising radiation sources for spectroscopy of unstable molecules.

AB - A triplet band system of C3 has been observed for the first time in absorption with a distributed-feedback (DFB) diode laser spectrometer and in emission with a Fourier transform spectrometer at around 6500 cm-1. The band has been assigned to the b approximately 3-PI-g-a approximately 3-PI-u system, and the spectroscopic constants in both the upper and lower states have been determined. It is demonstrated that near-infrared DFB lasers are promising radiation sources for spectroscopy of unstable molecules.

KW - FOURIER-TRANSFORM SPECTROSCOPY

KW - JET-COOLED C-3

KW - ELECTRONIC-TRANSITIONS

KW - LASER SPECTROSCOPY

KW - SPECTRUM

KW - C3

KW - MOLECULES

KW - ABINITIO

KW - STATES

KW - C2

M3 - Article

SN - 0021-9606

VL - 94

SP - 2401

EP - 2407

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 4

ER -