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A novel route to preussomerins via 2-arylacetal anions

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Publication details

JournalOrganic Letters
DatePublished - 1 Jun 2000
Issue number11
Volume2
Number of pages4
Pages (from-to)1613-1616
Original languageEnglish

Abstract

[GRAPHICS]

Dimerization of salicyladehydes provided 6H,12H-6,12-epoxydibenzo[b,f][1,5]dioxocins in multigram quantities. Deprotonation-allylation of the benzylic acetals followed by further functionalization of the diallyl derivative and double Friedel-Crafts cyclization gave a novel preussomerin analogue which possessed the full carbon skeleton of the natural products.

    Research areas

  • FUNGUS PREUSSIA-ISOMERA, ANTIFUNGAL METABOLITES

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