A novel Suzuki reaction system based on a supported palladium catalyst

E B  Mubofu; J H  Clark; D J  Macquarrie

A novel Suzuki reaction system based on a supported palladium catalyst

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A range of supported palladium complex-catalysed Suzuki reactions is described with notable features including fast and efficient reactions, excellent catalyst recyclability, and total catalyst stability under the reaction conditions. We have achieved turnover numbers of several thousand based on ten re-use experiments from batch reactions in air. Our system not only solves the basic problems of catalyst separation and recovery but also avoids the use of phosphine ligands.

Original language	English
Pages (from-to)	23-25
Number of pages	3
Journal	Green Chemistry
Volume	3
Issue number	1
Publication status	Published - Feb 2001

Keywords

CROSS-COUPLING REACTIONS
SILICA
EPOXIDATION
COMPLEXES
ACIDS

Cite this

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title = "A novel Suzuki reaction system based on a supported palladium catalyst",

abstract = "A range of supported palladium complex-catalysed Suzuki reactions is described with notable features including fast and efficient reactions, excellent catalyst recyclability, and total catalyst stability under the reaction conditions. We have achieved turnover numbers of several thousand based on ten re-use experiments from batch reactions in air. Our system not only solves the basic problems of catalyst separation and recovery but also avoids the use of phosphine ligands.",

keywords = "CROSS-COUPLING REACTIONS, SILICA, EPOXIDATION, COMPLEXES, ACIDS",

author = "Mubofu, {E B} and Clark, {J H} and Macquarrie, {D J}",

year = "2001",

month = feb,

language = "English",

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pages = "23--25",

journal = "Green Chemistry",

issn = "1463-9270",

publisher = "The Royal Society of Chemistry",

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T1 - A novel Suzuki reaction system based on a supported palladium catalyst

AU - Mubofu, E B

AU - Clark, J H

AU - Macquarrie, D J

PY - 2001/2

Y1 - 2001/2

N2 - A range of supported palladium complex-catalysed Suzuki reactions is described with notable features including fast and efficient reactions, excellent catalyst recyclability, and total catalyst stability under the reaction conditions. We have achieved turnover numbers of several thousand based on ten re-use experiments from batch reactions in air. Our system not only solves the basic problems of catalyst separation and recovery but also avoids the use of phosphine ligands.

AB - A range of supported palladium complex-catalysed Suzuki reactions is described with notable features including fast and efficient reactions, excellent catalyst recyclability, and total catalyst stability under the reaction conditions. We have achieved turnover numbers of several thousand based on ten re-use experiments from batch reactions in air. Our system not only solves the basic problems of catalyst separation and recovery but also avoids the use of phosphine ligands.

KW - CROSS-COUPLING REACTIONS

KW - SILICA

KW - EPOXIDATION

KW - COMPLEXES

KW - ACIDS

M3 - Article

SN - 1463-9270

VL - 3

SP - 23

EP - 25

JO - Green Chemistry

JF - Green Chemistry

IS - 1

ER -