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A parahydrogen based NMR study of Pt catalysed alkyne hydrogenation

Research output: Contribution to journalArticle

Published copy (DOI)

Author(s)

  • Marie Boutain
  • Simon B. Duckett
  • John P. Dunne
  • Cyril Godard
  • Jose M. Hernandez
  • A. Jonathan Holmes
  • Iman G. Khazal
  • Joaquin Lopez-Serrano

Department/unit(s)

Publication details

JournalDalton Transactions
DatePublished - 2010
Issue number14
Volume39
Number of pages6
Pages (from-to)3495-3500
Original languageEnglish

Abstract

A parahydrogen based NMR study of the platinum(II) bis-phosphine triflate catalysed hydrogenation of alkynes in methanol reveals that platinum bis-phosphine alkyl cations and methanol functionalised platinum bis-phosphine alkylether cations, are responsible for the observed alkene and vinylether products.

    Research areas

  • INORGANIC-CHEMISTRY, CRYSTAL-STRUCTURE, COMPLEXES

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