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A readily-accessible (+)-sparteine surrogate

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Publication details

JournalJournal of the American Chemical Society
DatePublished - 9 Oct 2002
Issue number40
Volume124
Number of pages2
Pages (from-to)11870-11871
Original languageEnglish

Abstract

A “(+)-sparteine-like” chiral diamine, readily synthesized in three steps from (-)-cytisine, has been evaluated in four different asymmetric transformations; in each case, selectivity in an enantiocomplementary fashion to (-)-sparteine was observed.

    Research areas

  • ASYMMETRIC LITHIATION-SUBSTITUTION, ENANTIOSELECTIVE DEPROTONATION, BOC-PYRROLIDINE, MOLECULAR-OXYGEN, CHIRAL DIAMINE, LEWIS-ACID, SPARTEINE, RESOLUTION, COMPLEXES, ALCOHOLS

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