A selective synthesis of the 1,3,4-triphospholide anion

C Fish; M Green; JC Jeffery; RJ Kilby; JM Lynam; CA Russell; CE Willans

doi:10.1021/om050766d

A selective synthesis of the 1,3,4-triphospholide anion

C Fish, M Green, JC Jeffery, RJ Kilby, JM Lynam, CA Russell, CE Willans

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Mg-2(mu-Cl)(3)(THF)(6)][2,5-((CBu)-Bu-t)(2)-1,3,4-P-3] and K[2,5-((CBU)-B-t)(2)-1,3,4-P-3] are formed quantitatively from reduction of the tricyclic-triphosphorus compound ClP3-((CBU)-B-t)(2) with Mg or K; the mechanistic insights gained from these studies lead to a new and "economic" synthesis of the [2,5-((CBU)-B-t)(2)-1,3,4-P-3](-) anion from the phosphalkyne (BuC)-Bu-t equivalent to P.

Original language	English
Pages (from-to)	5789-5791
Number of pages	3
Journal	Organometallics
Volume	24
Issue number	24
DOIs	https://doi.org/10.1021/om050766d
Publication status	Published - 21 Nov 2005

Keywords

TRANSITION-METAL
LIGANDS
BOND

Access to Document

10.1021/om050766d

Cite this

@article{a06b789c881948e0a05c7fc0678bf9f2,

title = "A selective synthesis of the 1,3,4-triphospholide anion",

abstract = "Mg-2(mu-Cl)(3)(THF)(6)][2,5-((CBu)-Bu-t)(2)-1,3,4-P-3] and K[2,5-((CBU)-B-t)(2)-1,3,4-P-3] are formed quantitatively from reduction of the tricyclic-triphosphorus compound ClP3-((CBU)-B-t)(2) with Mg or K; the mechanistic insights gained from these studies lead to a new and {"}economic{"} synthesis of the [2,5-((CBU)-B-t)(2)-1,3,4-P-3](-) anion from the phosphalkyne (BuC)-Bu-t equivalent to P.",

keywords = "TRANSITION-METAL, LIGANDS, BOND",

author = "C Fish and M Green and JC Jeffery and RJ Kilby and JM Lynam and CA Russell and CE Willans",

year = "2005",

month = nov,

day = "21",

doi = "10.1021/om050766d",

language = "English",

volume = "24",

pages = "5789--5791",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "24",

}

TY - JOUR

T1 - A selective synthesis of the 1,3,4-triphospholide anion

AU - Fish, C

AU - Green, M

AU - Jeffery, JC

AU - Kilby, RJ

AU - Lynam, JM

AU - Russell, CA

AU - Willans, CE

PY - 2005/11/21

Y1 - 2005/11/21

N2 - Mg-2(mu-Cl)(3)(THF)(6)][2,5-((CBu)-Bu-t)(2)-1,3,4-P-3] and K[2,5-((CBU)-B-t)(2)-1,3,4-P-3] are formed quantitatively from reduction of the tricyclic-triphosphorus compound ClP3-((CBU)-B-t)(2) with Mg or K; the mechanistic insights gained from these studies lead to a new and "economic" synthesis of the [2,5-((CBU)-B-t)(2)-1,3,4-P-3](-) anion from the phosphalkyne (BuC)-Bu-t equivalent to P.

AB - Mg-2(mu-Cl)(3)(THF)(6)][2,5-((CBu)-Bu-t)(2)-1,3,4-P-3] and K[2,5-((CBU)-B-t)(2)-1,3,4-P-3] are formed quantitatively from reduction of the tricyclic-triphosphorus compound ClP3-((CBU)-B-t)(2) with Mg or K; the mechanistic insights gained from these studies lead to a new and "economic" synthesis of the [2,5-((CBU)-B-t)(2)-1,3,4-P-3](-) anion from the phosphalkyne (BuC)-Bu-t equivalent to P.

KW - TRANSITION-METAL

KW - LIGANDS

KW - BOND

U2 - 10.1021/om050766d

DO - 10.1021/om050766d

M3 - Article

SN - 0276-7333

VL - 24

SP - 5789

EP - 5791

JO - Organometallics

JF - Organometallics

IS - 24

ER -