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From the same journal

A selective synthesis of the 1,3,4-triphospholide anion

Research output: Contribution to journalArticle

Published copy (DOI)

Author(s)

  • C Fish
  • M Green
  • J C Jeffery
  • R J Kilby
  • J M Lynam
  • C A Russell
  • C E Willans

Department/unit(s)

Publication details

JournalOrganometallics
DatePublished - 21 Nov 2005
Issue number24
Volume24
Number of pages3
Pages (from-to)5789-5791
Original languageEnglish

Abstract

Mg-2(mu-Cl)(3)(THF)(6)][2,5-((CBu)-Bu-t)(2)-1,3,4-P-3] and K[2,5-((CBU)-B-t)(2)-1,3,4-P-3] are formed quantitatively from reduction of the tricyclic-triphosphorus compound ClP3-((CBU)-B-t)(2) with Mg or K; the mechanistic insights gained from these studies lead to a new and "economic" synthesis of the [2,5-((CBU)-B-t)(2)-1,3,4-P-3](-) anion from the phosphalkyne (BuC)-Bu-t equivalent to P.

    Research areas

  • TRANSITION-METAL, LIGANDS, BOND

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