A SIMPLE AND EFFICIENT PROCEDURE FOR THE PREPARATION OF P-QUINOLS BY HYPERVALENT IODINE OXIDATION OF PHENOLS AND PHENOL TRIPROPYLSILYL ETHERS

A  MCKILLOP; L  MCLAREN; R J K  TAYLOR

A SIMPLE AND EFFICIENT PROCEDURE FOR THE PREPARATION OF P-QUINOLS BY HYPERVALENT IODINE OXIDATION OF PHENOLS AND PHENOL TRIPROPYLSILYL ETHERS

A MCKILLOP, L MCLAREN, R J K TAYLOR

Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

Oxidation of para-substituted phenols with [bis(trifluoroacetoxy) iodo]benzene (BTIB) in aqueous acetonitrile at 0 degrees C gives p-quinols in moderate to good yields; higher yields are obtained when tripropylsilyl ethers of phenols are used.

Original language	English
Pages (from-to)	2047-2048
Number of pages	2
Journal	Journal of the Chemical Society-Perkin Transactions 1
Issue number	15
Publication status	Published - 7 Aug 1994

Keywords

DIACETATE OXIDATION
(DIACETOXYIODO)BENZENE
CYCLIZATION
ARANOROSIN
SYSTEM

Cite this

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title = "A SIMPLE AND EFFICIENT PROCEDURE FOR THE PREPARATION OF P-QUINOLS BY HYPERVALENT IODINE OXIDATION OF PHENOLS AND PHENOL TRIPROPYLSILYL ETHERS",

abstract = "Oxidation of para-substituted phenols with [bis(trifluoroacetoxy) iodo]benzene (BTIB) in aqueous acetonitrile at 0 degrees C gives p-quinols in moderate to good yields; higher yields are obtained when tripropylsilyl ethers of phenols are used.",

keywords = "DIACETATE OXIDATION, (DIACETOXYIODO)BENZENE, CYCLIZATION, ARANOROSIN, SYSTEM",

author = "A MCKILLOP and L MCLAREN and TAYLOR, {R J K}",

year = "1994",

month = aug,

day = "7",

language = "English",

pages = "2047--2048",

journal = "Journal of the Chemical Society-Perkin Transactions 1",

issn = "0300-922X",

publisher = "Chemical Society",

number = "15",

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T1 - A SIMPLE AND EFFICIENT PROCEDURE FOR THE PREPARATION OF P-QUINOLS BY HYPERVALENT IODINE OXIDATION OF PHENOLS AND PHENOL TRIPROPYLSILYL ETHERS

AU - MCKILLOP, A

AU - MCLAREN, L

AU - TAYLOR, R J K

PY - 1994/8/7

Y1 - 1994/8/7

N2 - Oxidation of para-substituted phenols with [bis(trifluoroacetoxy) iodo]benzene (BTIB) in aqueous acetonitrile at 0 degrees C gives p-quinols in moderate to good yields; higher yields are obtained when tripropylsilyl ethers of phenols are used.

AB - Oxidation of para-substituted phenols with [bis(trifluoroacetoxy) iodo]benzene (BTIB) in aqueous acetonitrile at 0 degrees C gives p-quinols in moderate to good yields; higher yields are obtained when tripropylsilyl ethers of phenols are used.

KW - DIACETATE OXIDATION

KW - (DIACETOXYIODO)BENZENE

KW - CYCLIZATION

KW - ARANOROSIN

KW - SYSTEM

M3 - Comment/debate

SN - 0300-922X

SP - 2047

EP - 2048

JO - Journal of the Chemical Society-Perkin Transactions 1

JF - Journal of the Chemical Society-Perkin Transactions 1

IS - 15

ER -