A SIMPLE AND EFFICIENT PROCEDURE FOR THE PREPARATION OF P-QUINOLS BY HYPERVALENT IODINE OXIDATION OF PHENOLS AND PHENOL TRIPROPYLSILYL ETHERS

A MCKILLOP, L MCLAREN, R J K TAYLOR

Research output: Contribution to journalComment/debatepeer-review

Abstract

Oxidation of para-substituted phenols with [bis(trifluoroacetoxy) iodo]benzene (BTIB) in aqueous acetonitrile at 0 degrees C gives p-quinols in moderate to good yields; higher yields are obtained when tripropylsilyl ethers of phenols are used.

Original languageEnglish
Pages (from-to)2047-2048
Number of pages2
JournalJournal of the Chemical Society-Perkin Transactions 1
Issue number15
Publication statusPublished - 7 Aug 1994

Keywords

  • DIACETATE OXIDATION
  • (DIACETOXYIODO)BENZENE
  • CYCLIZATION
  • ARANOROSIN
  • SYSTEM

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