A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale

Timothy M Boyd; Kori A Andrea; Katherine Baston; Alice Johnson; David E Ryan; Andrew S Weller

doi:10.1039/c9cc08864d

A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale

Timothy M Boyd, Kori A Andrea, Katherine Baston, Alice Johnson, David E Ryan, Andrew S Weller

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A simple Co(ii)-based amine-borane dehydropolymerisation catalyst system is reported that operates at low loadings, to selectively give (H2BNMeH)n polymer on scale, with catalyst control over Mn, narrow dispersities and low residual metal content.

Original language	English
Pages (from-to)	482-485
Number of pages	4
Journal	Chemical communications
Volume	56
Issue number	3
Early online date	3 Dec 2019
DOIs	https://doi.org/10.1039/c9cc08864d
Publication status	Published - 2 Jan 2020

Bibliographical note

©The Royal Society of Chemistry 2020. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

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10.1039/c9cc08864d

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©The Royal Society of Chemistry 2020. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.
Accepted author manuscript, 2.55 MB

Putting Low Coordination into Practice by the Exploration of Metal-sigma-Interactions: Fundamentals, New Catalysts and Catalysis for New Materials
Weller, A. (Principal investigator)
EPSRC
1/01/20 → 31/03/22
Project: Research project (funded) › Research

Cite this

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abstract = "A simple Co(ii)-based amine-borane dehydropolymerisation catalyst system is reported that operates at low loadings, to selectively give (H2BNMeH)n polymer on scale, with catalyst control over Mn, narrow dispersities and low residual metal content.",

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AU - Ryan, David E

AU - Weller, Andrew S

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A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale

Abstract

Bibliographical note

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Projects

Putting Low Coordination into Practice by the Exploration of Metal-sigma-Interactions: Fundamentals, New Catalysts and Catalysis for New Materials

Cite this