Research output: Contribution to journal › Article › peer-review
Boyd_et_al-2020-Angewandte_Chemie_International_Edition
1.87 MB, PDF document
Journal | Angewandte Chemie International Edition |
---|---|
Date | Accepted/In press - 15 Jan 2020 |
Date | E-pub ahead of print - 20 Feb 2020 |
Date | Published (current) - 6 Apr 2020 |
Issue number | 15 |
Volume | 59 |
Pages (from-to) | 6177-6181 |
Early online date | 20/02/20 |
Original language | English |
The synthesis, and x-ray structure, of a cobalt s -alkane complex, [Co(Cy 2 P(CH 2 ) 4 PCy 2 )( norbornane )][BAr F 4 ], is achieved by a single-crystal to single-crystal solid/gas hydrogenation from a norbornadiene precursor. Magnetic data show this complex to be a triplet. Periodic DFT and electronic structure analyses identify weak C-H ··· Co σ -interactions, augmented by dispersive stabilisation between the alkane ligand and the anion-microenvironment. The calculations are most consistent with a η 1 : η 1 -alkane binding mode.
© 2020 The Authors.
Project: Research project (funded) › Research
Find related publications, people, projects, datasets and more using interactive charts.