A study of the A(2)Pi-X-2 Sigma(+) and B-2 Sigma(+)-X-2 Sigma(+) band systems of scandium monosulfide, ScS, using Fourier transform emission spectroscopy and laser excitation spectroscopy

Jamie Gengler; Jinhai Chen; T. C. Steimle; R. S. Ram; P. F. Bernath

doi:10.1016/j.jms.2006.02.006

A study of the A(2)Pi-X-2 Sigma(+) and B-2 Sigma(+)-X-2 Sigma(+) band systems of scandium monosulfide, ScS, using Fourier transform emission spectroscopy and laser excitation spectroscopy

Jamie Gengler, Jinhai Chen, T. C. Steimle, R. S. Ram, P. F. Bernath

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Emission spectra of the A(2)Pi(3/2)-X-2 Sigma(+) (0, 1), 1 (0, 0), and (1, 0) bands and the B-2 Sigma(+)-X-2 Sigma(+) (0,1), (0,0), (1,0), (2, 0), and (3, 1) bands of ScS have been recorded in the 10 000-13 500 cm(-1) region at a resolution of 0.05 cm(-1) using a Fourier transform (FT) spectrometer. The A(2)Pi(gamma)-X-2 Sigma(+) (1, 0) band as well as the B-2 Sigma(+)-X-2 Sigma(+) (0,0) and (1,0) bands have been recorded at high resolution (+/- 0.001 cm(-1)) by laser excitation spectroscopy using a supersonic molecular beam source. The FT spectral features range up to N = 148, while those recorded with the laser cover the "low-N" regions. The lines recorded with the laser exhibit splittings due to the Sc-45 (I = 7/2) magnetic hyperfine interactions, which are large (similar to 6.65 GHz) in the X-2 Sigma(+) state and much smaller in the B-2 Sigma(+) and A(2)Pi states. The energy levels were modeled using a traditional 'effective' Hamiltonian approach, and improved spectroscopic constants were extracted and compared with previous determinations and theoretical predictions. (C) 2006 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	36-45
Number of pages	10
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	237
Issue number	1
DOIs	https://doi.org/10.1016/j.jms.2006.02.006
Publication status	Published - May 2006

Keywords

scandium monosulfide
Fourier transform emission
laser excitation spectroscopy
ROTATIONAL ANALYSIS
HYPERFINE INTERACTIONS
DIPOLE-MOMENTS
MONOXIDE
SPECTRA
STATE

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10.1016/j.jms.2006.02.006

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@article{9af777bb4ec0455f942c720db591b0ef,

title = "A study of the A(2)Pi-X-2 Sigma(+) and B-2 Sigma(+)-X-2 Sigma(+) band systems of scandium monosulfide, ScS, using Fourier transform emission spectroscopy and laser excitation spectroscopy",

abstract = "Emission spectra of the A(2)Pi(3/2)-X-2 Sigma(+) (0, 1), 1 (0, 0), and (1, 0) bands and the B-2 Sigma(+)-X-2 Sigma(+) (0,1), (0,0), (1,0), (2, 0), and (3, 1) bands of ScS have been recorded in the 10 000-13 500 cm(-1) region at a resolution of 0.05 cm(-1) using a Fourier transform (FT) spectrometer. The A(2)Pi(gamma)-X-2 Sigma(+) (1, 0) band as well as the B-2 Sigma(+)-X-2 Sigma(+) (0,0) and (1,0) bands have been recorded at high resolution (+/- 0.001 cm(-1)) by laser excitation spectroscopy using a supersonic molecular beam source. The FT spectral features range up to N = 148, while those recorded with the laser cover the {"}low-N{"} regions. The lines recorded with the laser exhibit splittings due to the Sc-45 (I = 7/2) magnetic hyperfine interactions, which are large (similar to 6.65 GHz) in the X-2 Sigma(+) state and much smaller in the B-2 Sigma(+) and A(2)Pi states. The energy levels were modeled using a traditional 'effective' Hamiltonian approach, and improved spectroscopic constants were extracted and compared with previous determinations and theoretical predictions. (C) 2006 Elsevier Inc. All rights reserved.",

keywords = "scandium monosulfide, Fourier transform emission, laser excitation spectroscopy, ROTATIONAL ANALYSIS, HYPERFINE INTERACTIONS, DIPOLE-MOMENTS, MONOXIDE, SPECTRA, STATE",

author = "Jamie Gengler and Jinhai Chen and Steimle, {T. C.} and Ram, {R. S.} and Bernath, {P. F.}",

year = "2006",

month = may,

doi = "10.1016/j.jms.2006.02.006",

language = "English",

volume = "237",

pages = "36--45",

journal = "JOURNAL OF MOLECULAR SPECTROSCOPY",

issn = "0022-2852",

publisher = "Academic Press Inc.",

number = "1",

}

A study of the A(2)Pi-X-2 Sigma(+) and B-2 Sigma(+)-X-2 Sigma(+) band systems of scandium monosulfide, ScS, using Fourier transform emission spectroscopy and laser excitation spectroscopy. / Gengler, Jamie; Chen, Jinhai; Steimle, T. C. et al.
In: JOURNAL OF MOLECULAR SPECTROSCOPY, Vol. 237, No. 1, 05.2006, p. 36-45.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A study of the A(2)Pi-X-2 Sigma(+) and B-2 Sigma(+)-X-2 Sigma(+) band systems of scandium monosulfide, ScS, using Fourier transform emission spectroscopy and laser excitation spectroscopy

AU - Gengler, Jamie

AU - Chen, Jinhai

AU - Steimle, T. C.

AU - Ram, R. S.

AU - Bernath, P. F.

PY - 2006/5

Y1 - 2006/5

N2 - Emission spectra of the A(2)Pi(3/2)-X-2 Sigma(+) (0, 1), 1 (0, 0), and (1, 0) bands and the B-2 Sigma(+)-X-2 Sigma(+) (0,1), (0,0), (1,0), (2, 0), and (3, 1) bands of ScS have been recorded in the 10 000-13 500 cm(-1) region at a resolution of 0.05 cm(-1) using a Fourier transform (FT) spectrometer. The A(2)Pi(gamma)-X-2 Sigma(+) (1, 0) band as well as the B-2 Sigma(+)-X-2 Sigma(+) (0,0) and (1,0) bands have been recorded at high resolution (+/- 0.001 cm(-1)) by laser excitation spectroscopy using a supersonic molecular beam source. The FT spectral features range up to N = 148, while those recorded with the laser cover the "low-N" regions. The lines recorded with the laser exhibit splittings due to the Sc-45 (I = 7/2) magnetic hyperfine interactions, which are large (similar to 6.65 GHz) in the X-2 Sigma(+) state and much smaller in the B-2 Sigma(+) and A(2)Pi states. The energy levels were modeled using a traditional 'effective' Hamiltonian approach, and improved spectroscopic constants were extracted and compared with previous determinations and theoretical predictions. (C) 2006 Elsevier Inc. All rights reserved.

AB - Emission spectra of the A(2)Pi(3/2)-X-2 Sigma(+) (0, 1), 1 (0, 0), and (1, 0) bands and the B-2 Sigma(+)-X-2 Sigma(+) (0,1), (0,0), (1,0), (2, 0), and (3, 1) bands of ScS have been recorded in the 10 000-13 500 cm(-1) region at a resolution of 0.05 cm(-1) using a Fourier transform (FT) spectrometer. The A(2)Pi(gamma)-X-2 Sigma(+) (1, 0) band as well as the B-2 Sigma(+)-X-2 Sigma(+) (0,0) and (1,0) bands have been recorded at high resolution (+/- 0.001 cm(-1)) by laser excitation spectroscopy using a supersonic molecular beam source. The FT spectral features range up to N = 148, while those recorded with the laser cover the "low-N" regions. The lines recorded with the laser exhibit splittings due to the Sc-45 (I = 7/2) magnetic hyperfine interactions, which are large (similar to 6.65 GHz) in the X-2 Sigma(+) state and much smaller in the B-2 Sigma(+) and A(2)Pi states. The energy levels were modeled using a traditional 'effective' Hamiltonian approach, and improved spectroscopic constants were extracted and compared with previous determinations and theoretical predictions. (C) 2006 Elsevier Inc. All rights reserved.

KW - scandium monosulfide

KW - Fourier transform emission

KW - laser excitation spectroscopy

KW - ROTATIONAL ANALYSIS

KW - HYPERFINE INTERACTIONS

KW - DIPOLE-MOMENTS

KW - MONOXIDE

KW - SPECTRA

KW - STATE

U2 - 10.1016/j.jms.2006.02.006

DO - 10.1016/j.jms.2006.02.006

M3 - Article

SN - 0022-2852

VL - 237

SP - 36

EP - 45

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

JF - JOURNAL OF MOLECULAR SPECTROSCOPY

IS - 1

ER -