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A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)(2)(cyclopentane)

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JournalChemical Communications
DatePublished - 2009
Issue number11
Number of pages3
Pages (from-to)1401-1403
Original languageEnglish

Abstract

Short wavelength photolysis of (Tp)Re(CO)(3) (Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyclopentane yielded (Tp)Re(CO)(2)(cyclopentane), an alkane complex with three nitrogen ligands that was characterised by NMR spectroscopy.

    Research areas

  • RESOLVED INFRARED-SPECTROSCOPY, HYDROGEN BOND ACTIVATION, C-H, TRANSITION-METALS, SIGMA-COMPLEXES, LOW-TEMPERATURE, COORDINATION, PICOSECOND, RHENIUM, HEPTANE

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