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A tandem oxidation procedure for the conversion of alcohols into 1,1-dibromoalkenes

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JournalSynlett
DatePublished - 3 Apr 2004
Issue number5
Number of pages4
Pages (from-to)819-822
Original languageEnglish

Abstract

A practical and concise route to dibromoalkenes directly from activated alcohols in good to excellent yields using a new Tandem Oxidation Procedure (TOP) is reported. We also describe the use of these dibromoalkenes as intermediates in a one-pot route to 4,5-dihydro-1H-imidazoles and in the synthesis of bromoalkynes through MTBD-induced elimination.

    Research areas

  • dibromoalkenes, tandem oxidation procedure, one-pot, MTBD, WITTIG REACTIONS, MANGANESE-DIOXIDE, BUILDING-BLOCKS, ALDEHYDES, DERIVATIVES, 1,1-DIBROMO-1-ALKENES, CONSTRUCTION, APOPTOLIDIN, FRAGMENTS, ESTERS

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