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From the same journal

ACTIVATION OF H-2 BY CHLOROCARBONYLBIS(TRIMETHYLPHOSPHINE)RHODIUM(I) LABILIZES CO AND PRODUCES THE NEW BINUCLEAR COMPLEX H(CL)RH(PME3)2(MU-H)(MU-CL)RH(PME3)(CO)

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Publication details

JournalJOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
DatePublished - 7 Aug 1993
Issue number15
Number of pages3
Pages (from-to)1185-1187
Original languageEnglish

Abstract

The oxidative addition of H-2 to [RhCl(CO)(PMe3)2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

    Research areas

  • HYDROGEN-INDUCED POLARIZATION, TRANSFER-DEHYDROGENATION, PHOTOCHEMICAL DEHYDROGENATION, TRIMETHYLPHOSPHINE COMPLEXES, DIHYDROGEN ATMOSPHERE, H ACTIVATION, ALKANES, RHODIUM, RHCL(CO)(PME3)2, CARBONYLATION

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