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Addition of H-2 to a cationic iridium(I) complex: a study using parahydrogen NMR

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JournalJOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
DatePublished - 2000
Issue number14
Number of pages3
Pages (from-to)2251-2253
Original languageEnglish

Abstract

Parahydrogen enhanced NMR signals are used to monitor the reaction between the cationic iridium(I) complex [Ir(BPM)(CO)(2)][BPh4] (BPM = bis(pyrazol-1-yl)methane) and dihydrogen: four major products are formed in a cascade of reactions.

    Research areas

  • HETERONUCLEAR COUPLING-CONSTANTS, TRANSITION-METAL COMPLEXES, INDUCED POLARIZATION, PARA-HYDROGEN, ENHANCEMENT, C-13

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