Addition of trichloromethyl radicals to alkenes: The use of phosphites as hydrogen-atom donors in intermolecular radical reactions

J M  Barks; B C  Gilbert; A F  Parsons; B  Upeandran

Addition of trichloromethyl radicals to alkenes: The use of phosphites as hydrogen-atom donors in intermolecular radical reactions

J M Barks, B C Gilbert, A F Parsons, B Upeandran

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Addition of trichloromethyl radicals (generated from BrCCl3 or CCl4) to a variety of alkenes in the presence of hydrogen-atom donors has been explored. The use of phosphites as hydrogen-atom donors was shown to provide a mild, novel and technically clean approach to trichloroalkanes.

Original language	English
Pages (from-to)	1719-1722
Number of pages	4
Journal	Synlett
Issue number	11
Publication status	Published - Nov 2001

Keywords

addition reactions
alkenes
phosphorus
radicals
radical reactions
KHARASCH ADDITION
CONTROLLED POLYMERIZATION
PHOSPHONYL RADICALS
EFFICIENT
CHLOROFORM
COMPLEXES
ALCOHOLS
KETONES
OLEFINS
ESTERS

Cite this

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title = "Addition of trichloromethyl radicals to alkenes: The use of phosphites as hydrogen-atom donors in intermolecular radical reactions",

abstract = "Addition of trichloromethyl radicals (generated from BrCCl3 or CCl4) to a variety of alkenes in the presence of hydrogen-atom donors has been explored. The use of phosphites as hydrogen-atom donors was shown to provide a mild, novel and technically clean approach to trichloroalkanes.",

keywords = "addition reactions, alkenes, phosphorus, radicals, radical reactions, KHARASCH ADDITION, CONTROLLED POLYMERIZATION, PHOSPHONYL RADICALS, EFFICIENT, CHLOROFORM, COMPLEXES, ALCOHOLS, KETONES, OLEFINS, ESTERS",

author = "Barks, {J M} and Gilbert, {B C} and Parsons, {A F} and B Upeandran",

year = "2001",

month = nov,

language = "English",

pages = "1719--1722",

journal = "Synlett",

issn = "1437-2096",

publisher = "Georg Thieme Verlag",

number = "11",

}

TY - JOUR

T1 - Addition of trichloromethyl radicals to alkenes: The use of phosphites as hydrogen-atom donors in intermolecular radical reactions

AU - Barks, J M

AU - Gilbert, B C

AU - Parsons, A F

AU - Upeandran, B

PY - 2001/11

Y1 - 2001/11

N2 - Addition of trichloromethyl radicals (generated from BrCCl3 or CCl4) to a variety of alkenes in the presence of hydrogen-atom donors has been explored. The use of phosphites as hydrogen-atom donors was shown to provide a mild, novel and technically clean approach to trichloroalkanes.

AB - Addition of trichloromethyl radicals (generated from BrCCl3 or CCl4) to a variety of alkenes in the presence of hydrogen-atom donors has been explored. The use of phosphites as hydrogen-atom donors was shown to provide a mild, novel and technically clean approach to trichloroalkanes.

KW - addition reactions

KW - alkenes

KW - phosphorus

KW - radicals

KW - radical reactions

KW - KHARASCH ADDITION

KW - CONTROLLED POLYMERIZATION

KW - PHOSPHONYL RADICALS

KW - EFFICIENT

KW - CHLOROFORM

KW - COMPLEXES

KW - ALCOHOLS

KW - KETONES

KW - OLEFINS

KW - ESTERS

M3 - Article

SP - 1719

EP - 1722

JO - Synlett

JF - Synlett

SN - 1437-2096

IS - 11

ER -