ADSORPTION STUDIES OF DIFFERENT END-FUNCTIONALIZED LINEAR POLY(DIMETHYLSILOXANE)

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ADSORPTION STUDIES OF DIFFERENT END-FUNCTIONALIZED LINEAR POLY(DIMETHYLSILOXANE). / Patel, A; Cosgrove, T; Semlyen, J A; Webster, J R P; Scheutjens, J M H M.

In: Colloids and surfaces a-Physicochemical and engineering aspects, Vol. 87, No. 1, 28.07.1994, p. 15-24.

Research output: Contribution to journalArticle

Harvard

Patel, A, Cosgrove, T, Semlyen, JA, Webster, JRP & Scheutjens, JMHM 1994, 'ADSORPTION STUDIES OF DIFFERENT END-FUNCTIONALIZED LINEAR POLY(DIMETHYLSILOXANE)', Colloids and surfaces a-Physicochemical and engineering aspects, vol. 87, no. 1, pp. 15-24.

APA

Patel, A., Cosgrove, T., Semlyen, J. A., Webster, J. R. P., & Scheutjens, J. M. H. M. (1994). ADSORPTION STUDIES OF DIFFERENT END-FUNCTIONALIZED LINEAR POLY(DIMETHYLSILOXANE). Colloids and surfaces a-Physicochemical and engineering aspects, 87(1), 15-24.

Vancouver

Patel A, Cosgrove T, Semlyen JA, Webster JRP, Scheutjens JMHM. ADSORPTION STUDIES OF DIFFERENT END-FUNCTIONALIZED LINEAR POLY(DIMETHYLSILOXANE). Colloids and surfaces a-Physicochemical and engineering aspects. 1994 Jul 28;87(1):15-24.

Author

Patel, A ; Cosgrove, T ; Semlyen, J A ; Webster, J R P ; Scheutjens, J M H M. / ADSORPTION STUDIES OF DIFFERENT END-FUNCTIONALIZED LINEAR POLY(DIMETHYLSILOXANE). In: Colloids and surfaces a-Physicochemical and engineering aspects. 1994 ; Vol. 87, No. 1. pp. 15-24.

Bibtex - Download

@article{f5d2dcd93d654da794dd5a1d324e9368,
title = "ADSORPTION STUDIES OF DIFFERENT END-FUNCTIONALIZED LINEAR POLY(DIMETHYLSILOXANE)",
abstract = "The adsorption of end-functionalised poly(dimethylsiloxane) (PDMS), of both low and high molecular weight, on to silica and alumina from carbon tetrachloride has been investigated by Fourier transform infrared spectroscopy. It was found that the adsorbed amounts of these end-functionalised PDMS depend strongly on the composition of the polymer; samples with end groups having a high surface affinity were found to adsorb to a greater extent. Detailed information on the structure of the adsorbed layer obtained by the Scheutjens-Fleer theoretical model and a Monte Carlo simulation indicated that polymers with such end groups adsorb primarily as loops, with fewer segments in trains and tails compared with a homopolymer. Adsorption was found to be greater on alumina than on silica for both molecular weight series.",
keywords = "ADSORPTION, ALUMINA, FOURIER TRANSFORM INFRARED SPECTROSCOPY, FUNCTIONAL END GROUPS, LOOPS, SCHEUTJENS-FLEER MODEL, SILICA, CHAINS, COPOLYMERS, INTERFACE, KINETICS, MIXTURES, SURFACES, SOLVENT, MODEL",
author = "A Patel and T Cosgrove and Semlyen, {J A} and Webster, {J R P} and Scheutjens, {J M H M}",
year = "1994",
month = "7",
day = "28",
language = "English",
volume = "87",
pages = "15--24",
journal = "Colloids and surfaces a-Physicochemical and engineering aspects",
issn = "0927-7757",
publisher = "Elsevier",
number = "1",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - ADSORPTION STUDIES OF DIFFERENT END-FUNCTIONALIZED LINEAR POLY(DIMETHYLSILOXANE)

AU - Patel, A

AU - Cosgrove, T

AU - Semlyen, J A

AU - Webster, J R P

AU - Scheutjens, J M H M

PY - 1994/7/28

Y1 - 1994/7/28

N2 - The adsorption of end-functionalised poly(dimethylsiloxane) (PDMS), of both low and high molecular weight, on to silica and alumina from carbon tetrachloride has been investigated by Fourier transform infrared spectroscopy. It was found that the adsorbed amounts of these end-functionalised PDMS depend strongly on the composition of the polymer; samples with end groups having a high surface affinity were found to adsorb to a greater extent. Detailed information on the structure of the adsorbed layer obtained by the Scheutjens-Fleer theoretical model and a Monte Carlo simulation indicated that polymers with such end groups adsorb primarily as loops, with fewer segments in trains and tails compared with a homopolymer. Adsorption was found to be greater on alumina than on silica for both molecular weight series.

AB - The adsorption of end-functionalised poly(dimethylsiloxane) (PDMS), of both low and high molecular weight, on to silica and alumina from carbon tetrachloride has been investigated by Fourier transform infrared spectroscopy. It was found that the adsorbed amounts of these end-functionalised PDMS depend strongly on the composition of the polymer; samples with end groups having a high surface affinity were found to adsorb to a greater extent. Detailed information on the structure of the adsorbed layer obtained by the Scheutjens-Fleer theoretical model and a Monte Carlo simulation indicated that polymers with such end groups adsorb primarily as loops, with fewer segments in trains and tails compared with a homopolymer. Adsorption was found to be greater on alumina than on silica for both molecular weight series.

KW - ADSORPTION

KW - ALUMINA

KW - FOURIER TRANSFORM INFRARED SPECTROSCOPY

KW - FUNCTIONAL END GROUPS

KW - LOOPS

KW - SCHEUTJENS-FLEER MODEL

KW - SILICA

KW - CHAINS

KW - COPOLYMERS

KW - INTERFACE

KW - KINETICS

KW - MIXTURES

KW - SURFACES

KW - SOLVENT

KW - MODEL

M3 - Article

VL - 87

SP - 15

EP - 24

JO - Colloids and surfaces a-Physicochemical and engineering aspects

T2 - Colloids and surfaces a-Physicochemical and engineering aspects

JF - Colloids and surfaces a-Physicochemical and engineering aspects

SN - 0927-7757

IS - 1

ER -