An anomalously large nuclear overhauser effect in the 13C n.m.r. spectra of strongly hydrogen-bonded systems

Jack M. Miller; Raveendran K. Kanippayoor; James H. Clark; John Emsley

doi:10.1039/C39790000758

An anomalously large nuclear overhauser effect in the ¹³C n.m.r. spectra of strongly hydrogen-bonded systems

Jack M. Miller^*, Raveendran K. Kanippayoor, James H. Clark, John Emsley

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The carboxy carbons of neat liquid carboxylic acids display an anomalously large nuclear Overhauser Effect that is further enhanced by the addition of potassium fluoride which is capable of forming strong hydrogen bonds between the fluoride anion and the acid hydroxy group.

Original language	English
Pages (from-to)	758-759
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39790000758
Publication status	Published - 1 Dec 1979

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@article{e7543fa795604a7f8d736151f0bc807a,

title = "An anomalously large nuclear overhauser effect in the 13C n.m.r. spectra of strongly hydrogen-bonded systems",

abstract = "The carboxy carbons of neat liquid carboxylic acids display an anomalously large nuclear Overhauser Effect that is further enhanced by the addition of potassium fluoride which is capable of forming strong hydrogen bonds between the fluoride anion and the acid hydroxy group.",

author = "Miller, {Jack M.} and Kanippayoor, {Raveendran K.} and Clark, {James H.} and John Emsley",

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T1 - An anomalously large nuclear overhauser effect in the 13C n.m.r. spectra of strongly hydrogen-bonded systems

AU - Miller, Jack M.

AU - Kanippayoor, Raveendran K.

AU - Clark, James H.

AU - Emsley, John

PY - 1979/12/1

Y1 - 1979/12/1

N2 - The carboxy carbons of neat liquid carboxylic acids display an anomalously large nuclear Overhauser Effect that is further enhanced by the addition of potassium fluoride which is capable of forming strong hydrogen bonds between the fluoride anion and the acid hydroxy group.

AB - The carboxy carbons of neat liquid carboxylic acids display an anomalously large nuclear Overhauser Effect that is further enhanced by the addition of potassium fluoride which is capable of forming strong hydrogen bonds between the fluoride anion and the acid hydroxy group.

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U2 - 10.1039/C39790000758

DO - 10.1039/C39790000758

M3 - Article

AN - SCOPUS:37049100049

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

An anomalously large nuclear overhauser effect in the 13C n.m.r. spectra of strongly hydrogen-bonded systems

Abstract

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An anomalously large nuclear overhauser effect in the ¹³C n.m.r. spectra of strongly hydrogen-bonded systems