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From the same journal

ANION RECOGNITION BY REDOX-RESPONSIVE DITOPIC BIS-COBALTOCENIUM RECEPTOR MOLECULES INCLUDING A NOVEL CALIX[4]ARENE DERIVATIVE THAT BINDS A DICARBOXYLATE DIANION

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Standard

ANION RECOGNITION BY REDOX-RESPONSIVE DITOPIC BIS-COBALTOCENIUM RECEPTOR MOLECULES INCLUDING A NOVEL CALIX[4]ARENE DERIVATIVE THAT BINDS A DICARBOXYLATE DIANION. / BEER, P D ; HESEK, D ; KINGSTON, J E ; SMITH, D K ; STOKES, S E ; DREW, M G B .

In: Organometallics, Vol. 14, No. 7, 07.1995, p. 3288-3295.

Research output: Contribution to journalArticle

Harvard

BEER, PD, HESEK, D, KINGSTON, JE, SMITH, DK, STOKES, SE & DREW, MGB 1995, 'ANION RECOGNITION BY REDOX-RESPONSIVE DITOPIC BIS-COBALTOCENIUM RECEPTOR MOLECULES INCLUDING A NOVEL CALIX[4]ARENE DERIVATIVE THAT BINDS A DICARBOXYLATE DIANION', Organometallics, vol. 14, no. 7, pp. 3288-3295.

APA

BEER, P. D., HESEK, D., KINGSTON, J. E., SMITH, D. K., STOKES, S. E., & DREW, M. G. B. (1995). ANION RECOGNITION BY REDOX-RESPONSIVE DITOPIC BIS-COBALTOCENIUM RECEPTOR MOLECULES INCLUDING A NOVEL CALIX[4]ARENE DERIVATIVE THAT BINDS A DICARBOXYLATE DIANION. Organometallics, 14(7), 3288-3295.

Vancouver

BEER PD, HESEK D, KINGSTON JE, SMITH DK, STOKES SE, DREW MGB. ANION RECOGNITION BY REDOX-RESPONSIVE DITOPIC BIS-COBALTOCENIUM RECEPTOR MOLECULES INCLUDING A NOVEL CALIX[4]ARENE DERIVATIVE THAT BINDS A DICARBOXYLATE DIANION. Organometallics. 1995 Jul;14(7):3288-3295.

Author

BEER, P D ; HESEK, D ; KINGSTON, J E ; SMITH, D K ; STOKES, S E ; DREW, M G B . / ANION RECOGNITION BY REDOX-RESPONSIVE DITOPIC BIS-COBALTOCENIUM RECEPTOR MOLECULES INCLUDING A NOVEL CALIX[4]ARENE DERIVATIVE THAT BINDS A DICARBOXYLATE DIANION. In: Organometallics. 1995 ; Vol. 14, No. 7. pp. 3288-3295.

Bibtex - Download

@article{39ff7623b0884d81be18585cfe2deb4d,
title = "ANION RECOGNITION BY REDOX-RESPONSIVE DITOPIC BIS-COBALTOCENIUM RECEPTOR MOLECULES INCLUDING A NOVEL CALIX[4]ARENE DERIVATIVE THAT BINDS A DICARBOXYLATE DIANION",
abstract = "A series of novel ditopic bis-cobaltocenium receptor molecules containing alkyl, aryl, and calix[4]arene spacers have been synthesized via the reaction of the new synthon 1-(ethylcarboxy)-1'-(chlorocarbonyl)cobaltocenium chloride (3) or 1-(chloro carbonyl)cobaltocenium chloride (9) with the appropriate diamine. Proton NMR halide anion coordination studies reveal that the ethyl- (4), propyl- (5), and butyl-linked (6) derivatives form 1:1 stoichiometric complexes in acetonitrile solutions. Stability constant determinations suggest that the ethyl derivative 4 exhibits selectivity for the chloride anion in preference to bromide or iodide. Receptors containing larger aryl (7,8,10) and alkylamino (11) spacers form complexes of2:1 halide anion:receptor stoichiometry. An X-ray crystal structure of the bis-cobaltocenium calix[4]arene derivative 15 is described. This receptor forms extremely stable 1:1 anion complexes with chloride, bromide, and H2PO4- in dimethylsulfoxide solutions and with the dicarboxylate dianion adipate in acetone. Ah the bis-cobaltocenium systems were found to display electrochemical recognition of varied anion guests, as shown by cyclic voltammetric experiments. Receptor 15 was also found to redox-respond to the presence of adipate.",
keywords = "POLYAMMONIUM MACROCYCLES, SELECTIVITY, CHLORIDE, SITES",
author = "BEER, {P D} and D HESEK and KINGSTON, {J E} and SMITH, {D K} and STOKES, {S E} and DREW, {M G B}",
year = "1995",
month = "7",
language = "English",
volume = "14",
pages = "3288--3295",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "7",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - ANION RECOGNITION BY REDOX-RESPONSIVE DITOPIC BIS-COBALTOCENIUM RECEPTOR MOLECULES INCLUDING A NOVEL CALIX[4]ARENE DERIVATIVE THAT BINDS A DICARBOXYLATE DIANION

AU - BEER, P D

AU - HESEK, D

AU - KINGSTON, J E

AU - SMITH, D K

AU - STOKES, S E

AU - DREW, M G B

PY - 1995/7

Y1 - 1995/7

N2 - A series of novel ditopic bis-cobaltocenium receptor molecules containing alkyl, aryl, and calix[4]arene spacers have been synthesized via the reaction of the new synthon 1-(ethylcarboxy)-1'-(chlorocarbonyl)cobaltocenium chloride (3) or 1-(chloro carbonyl)cobaltocenium chloride (9) with the appropriate diamine. Proton NMR halide anion coordination studies reveal that the ethyl- (4), propyl- (5), and butyl-linked (6) derivatives form 1:1 stoichiometric complexes in acetonitrile solutions. Stability constant determinations suggest that the ethyl derivative 4 exhibits selectivity for the chloride anion in preference to bromide or iodide. Receptors containing larger aryl (7,8,10) and alkylamino (11) spacers form complexes of2:1 halide anion:receptor stoichiometry. An X-ray crystal structure of the bis-cobaltocenium calix[4]arene derivative 15 is described. This receptor forms extremely stable 1:1 anion complexes with chloride, bromide, and H2PO4- in dimethylsulfoxide solutions and with the dicarboxylate dianion adipate in acetone. Ah the bis-cobaltocenium systems were found to display electrochemical recognition of varied anion guests, as shown by cyclic voltammetric experiments. Receptor 15 was also found to redox-respond to the presence of adipate.

AB - A series of novel ditopic bis-cobaltocenium receptor molecules containing alkyl, aryl, and calix[4]arene spacers have been synthesized via the reaction of the new synthon 1-(ethylcarboxy)-1'-(chlorocarbonyl)cobaltocenium chloride (3) or 1-(chloro carbonyl)cobaltocenium chloride (9) with the appropriate diamine. Proton NMR halide anion coordination studies reveal that the ethyl- (4), propyl- (5), and butyl-linked (6) derivatives form 1:1 stoichiometric complexes in acetonitrile solutions. Stability constant determinations suggest that the ethyl derivative 4 exhibits selectivity for the chloride anion in preference to bromide or iodide. Receptors containing larger aryl (7,8,10) and alkylamino (11) spacers form complexes of2:1 halide anion:receptor stoichiometry. An X-ray crystal structure of the bis-cobaltocenium calix[4]arene derivative 15 is described. This receptor forms extremely stable 1:1 anion complexes with chloride, bromide, and H2PO4- in dimethylsulfoxide solutions and with the dicarboxylate dianion adipate in acetone. Ah the bis-cobaltocenium systems were found to display electrochemical recognition of varied anion guests, as shown by cyclic voltammetric experiments. Receptor 15 was also found to redox-respond to the presence of adipate.

KW - POLYAMMONIUM MACROCYCLES

KW - SELECTIVITY

KW - CHLORIDE

KW - SITES

M3 - Article

VL - 14

SP - 3288

EP - 3295

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 7

ER -