Abstract
Two novel succinimide-based palladium complexes, AsCat and FurCat, are highly efficient catalysts for room-temperature Stille cross-coupling of organostannanes with benzyl chlorides. The air- and moisture-stable catalysts are prepared in one step, and the coupling reactions proceed with a high selectivity for the benzyl position under mild conditions without the need for additives.
Original language | English |
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Journal | Chemical communications |
Volume | 51 |
Issue number | 16 |
Early online date | 28 Jan 2015 |
DOIs | |
Publication status | Published - 25 Feb 2015 |