Bending and shaping: cubics, calamitics and columnars

D Fazio, C Mongin, B Donnio, Y Galerne, D Guillon, D W Bruce

Research output: Contribution to journalArticlepeer-review

Abstract

The mesomorphism of a series of complexes of Pd( II), Pt( II) and Ag( I) is discussed and systematic structural variations are highlighted which lead to an appreciation of important factors determining the liquid-crystalline polymorphism of these complexes. Models are proposed for cubic phase formation and the occurrence of an unusual lamellar phase in-between a SmC and a columnar phase is discussed.

Original languageEnglish
Pages (from-to)2852-2863
Number of pages12
JournalJournal of Materials Chemistry
Volume11
Issue number11
Publication statusPublished - 2001

Keywords

  • TRANSITION-METAL COMPLEXES
  • X-RAY-DIFFRACTION
  • LIQUID-CRYSTALS
  • POLYCATENAR MESOGENS
  • MOLECULAR DESIGN
  • MESOPHASES
  • PHASE
  • MESOMORPHISM
  • SILVER(I)
  • ALKOXYSTILBAZOLES

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