BODIPY-thiophene copolymers as p-channel semiconductors for organic thin-film transistors

Hakan Usta, M Deniz Yilmaz, Alyssa-Jennifer Avestro, Damien Boudinet, Mitchell Denti, Wei Zhao, J Fraser Stoddart, Antonio Facchetti

Research output: Contribution to journalArticlepeer-review


The synthesis and physicochemical properties of a new class of BODIPY-based donor-acceptor π-conjugated polymers are presented. Solution-processed top-gate/bottom-contact (TG-BC) thin-film transistors on flexible plastic substrates exhibit air-stable p-channel activities with charge carrier mobilities as high as 0.17 cm(2) /V·s and current on/off ratios of 10(5) -10(6) , the highest reported to date for a BODIPY-based semiconductor. The results shown here indicate a significant charge-transport improvement (>10000×) in BODIPY-based polymeric semiconductors, demonstrating its potential in future organic optoelectronic applications.

Original languageEnglish
Pages (from-to)4327-34
Number of pages8
JournalAdvanced Materials
Issue number31
Publication statusPublished - 21 Aug 2013

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