Calamitics, cubics, and columnars - Liquid-crystalline complexes of silver(I) - Research Database, The University of York

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Calamitics, cubics, and columnars - Liquid-crystalline complexes of silver(I)

Research output: Contribution to journal › Literature review › peer-review

Published copy (DOI)

10.1021/ar990159k

Author(s)

D W Bruce

Department/unit(s)

Chemistry

Publication details

Journal	ACCOUNTS OF CHEMICAL RESEARCH
Date	Published - Dec 2000
Issue number	12
Volume	33
Number of pages	10
Pages (from-to)	831-840
Original language	English

Abstract

The study of metallomesogens has added several new dimensions to the wider field of liquid crystals. In this Account, just one family of complexes is considered, namely alkoxystilbazole complexes of various silver(I) salts. These complexes show an incredibly rich and diverse mesomorphism ranging from nematic and smectic to columnar phases; in particular, many complexes show the still rare thermotropic cubic phase. Through systematic structural variations, it has been possible to gain a good understanding of the factors influencing the behavior of these fascinating systems.

Research areas

MESOMORPHIC STILBAZOLE COMPLEXES, X-RAY-DIFFRACTION, PHASE-TRANSITIONS, MESOPHASES, MESOGENS, SULFATE, ALKOXYSTILBAZOLES, BILAYERS, LIGAND, ANION

Activities

9th Ibero-American Workshop on Liquid Crystals
Activity: Talk or presentation › Workshop

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