CAN-mediated oxidative free radical reactions in an ionic liquid

G  Bar; F  Bini; A F  Parsons

doi:10.1081/SCC-120015703

CAN-mediated oxidative free radical reactions in an ionic liquid

G Bar, F Bini, A F Parsons

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Cerium(IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1,3-dicarbonyl precursors, which can be utilized in these carbon-carbon bond-forming reactions.

Original language	English
Pages (from-to)	213-222
Number of pages	10
Journal	SYNTHETIC COMMUNICATIONS
Volume	33
Issue number	2
DOIs	https://doi.org/10.1081/SCC-120015703
Publication status	Published - 2003

Keywords

radical reactions
ionic liquids
CERIUM(IV) AMMONIUM-NITRATE
MANGANESE(III) ACETATE
1,3-DICARBONYL COMPOUNDS
QUINOLINE ALKALOIDS
EFFICIENT SYNTHESIS
ALKENES
CYCLIZATION
DIHYDROFUROQUINOLINONES
FUROQUINOLINONES
CYCLOADDITION

Access to Document

10.1081/SCC-120015703

Cite this

@article{137614340cda4b4d9e3e0de0cf3b5a68,

title = "CAN-mediated oxidative free radical reactions in an ionic liquid",

abstract = "Cerium(IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1,3-dicarbonyl precursors, which can be utilized in these carbon-carbon bond-forming reactions.",

keywords = "radical reactions, ionic liquids, CERIUM(IV) AMMONIUM-NITRATE, MANGANESE(III) ACETATE, 1,3-DICARBONYL COMPOUNDS, QUINOLINE ALKALOIDS, EFFICIENT SYNTHESIS, ALKENES, CYCLIZATION, DIHYDROFUROQUINOLINONES, FUROQUINOLINONES, CYCLOADDITION",

author = "G Bar and F Bini and Parsons, {A F}",

year = "2003",

doi = "10.1081/SCC-120015703",

language = "English",

volume = "33",

pages = "213--222",

journal = "SYNTHETIC COMMUNICATIONS",

issn = "0039-7911",

publisher = "Taylor & Francis",

number = "2",

}

TY - JOUR

T1 - CAN-mediated oxidative free radical reactions in an ionic liquid

AU - Bar, G

AU - Bini, F

AU - Parsons, A F

PY - 2003

Y1 - 2003

N2 - Cerium(IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1,3-dicarbonyl precursors, which can be utilized in these carbon-carbon bond-forming reactions.

AB - Cerium(IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1,3-dicarbonyl precursors, which can be utilized in these carbon-carbon bond-forming reactions.

KW - radical reactions

KW - ionic liquids

KW - CERIUM(IV) AMMONIUM-NITRATE

KW - MANGANESE(III) ACETATE

KW - 1,3-DICARBONYL COMPOUNDS

KW - QUINOLINE ALKALOIDS

KW - EFFICIENT SYNTHESIS

KW - ALKENES

KW - CYCLIZATION

KW - DIHYDROFUROQUINOLINONES

KW - FUROQUINOLINONES

KW - CYCLOADDITION

U2 - 10.1081/SCC-120015703

DO - 10.1081/SCC-120015703

M3 - Article

VL - 33

SP - 213

EP - 222

JO - SYNTHETIC COMMUNICATIONS

JF - SYNTHETIC COMMUNICATIONS

SN - 0039-7911

IS - 2

ER -