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CAN-mediated oxidative free radical reactions in an ionic liquid

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JournalSYNTHETIC COMMUNICATIONS
DatePublished - 2003
Issue number2
Volume33
Number of pages10
Pages (from-to)213-222
Original languageEnglish

Abstract

Cerium(IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1,3-dicarbonyl precursors, which can be utilized in these carbon-carbon bond-forming reactions.

    Research areas

  • radical reactions, ionic liquids, CERIUM(IV) AMMONIUM-NITRATE, MANGANESE(III) ACETATE, 1,3-DICARBONYL COMPOUNDS, QUINOLINE ALKALOIDS, EFFICIENT SYNTHESIS, ALKENES, CYCLIZATION, DIHYDROFUROQUINOLINONES, FUROQUINOLINONES, CYCLOADDITION

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