Cascade reactions of substituted 1,2,4-triazines: Rapid access to nitrogen-containing polycycles

S A Raw; R J K Taylor

doi:10.1021/ja045780g

Cascade reactions of substituted 1,2,4-triazines: Rapid access to nitrogen-containing polycycles

S A Raw, R J K Taylor

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A new and straightforward methodology for the construction of complex nitrogen-containing polycycles has been developed. This methodology exploits easily prepared 1,2,4-triazines as substrates for a pericyclic reaction cascade, forming the polycycles in good to excellent yield in a single operation.

Original language	English
Pages (from-to)	12260-12261
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	39
DOIs	https://doi.org/10.1021/ja045780g
Publication status	Published - 6 Oct 2004

Keywords

DIELS-ALDER REACTION
OXIDATION-WITTIG REACTIONS
HETEROCYCLIC AZADIENES
ENAMINES
PYRIDINES

Access to Document

10.1021/ja045780g

http://dx.doi.org/10.1021/ja045780g

Cite this

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title = "Cascade reactions of substituted 1,2,4-triazines: Rapid access to nitrogen-containing polycycles",

abstract = "A new and straightforward methodology for the construction of complex nitrogen-containing polycycles has been developed. This methodology exploits easily prepared 1,2,4-triazines as substrates for a pericyclic reaction cascade, forming the polycycles in good to excellent yield in a single operation.",

keywords = "DIELS-ALDER REACTION, OXIDATION-WITTIG REACTIONS, HETEROCYCLIC AZADIENES, ENAMINES, PYRIDINES",

author = "Raw, {S A} and Taylor, {R J K}",

year = "2004",

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AU - Raw, S A

AU - Taylor, R J K

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N2 - A new and straightforward methodology for the construction of complex nitrogen-containing polycycles has been developed. This methodology exploits easily prepared 1,2,4-triazines as substrates for a pericyclic reaction cascade, forming the polycycles in good to excellent yield in a single operation.

AB - A new and straightforward methodology for the construction of complex nitrogen-containing polycycles has been developed. This methodology exploits easily prepared 1,2,4-triazines as substrates for a pericyclic reaction cascade, forming the polycycles in good to excellent yield in a single operation.

KW - DIELS-ALDER REACTION

KW - OXIDATION-WITTIG REACTIONS

KW - HETEROCYCLIC AZADIENES

KW - ENAMINES

KW - PYRIDINES

U2 - 10.1021/ja045780g

DO - 10.1021/ja045780g

M3 - Article

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VL - 126

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EP - 12261

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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